Volcanic Islands

Rocks of the lowest series.

A calcareous sedimentary deposit, with recent shells, altered by the

contact of superincumbent lava, its horizontality and extent.

Subsequent volcanic eruptions, associated with calcareous matter in an

earthy and fibrous form, and often enclosed within the separate cells of

the scoriae.

Ancient and obliterated orifices of eruption of small size.

Difficulty of tracing over a bare plain recent streams of lava.

Inland hills of more ancient volcanic rock.

Decomposed olivine in large masses.

Feldspathic rocks beneath the upper crystalline basaltic strata.

Uniform structure and form of the more ancient volcanic hills.

Form of the valleys near the coast.

Conglomerate now forming on the sea beach.

(FIGURE 1: MAP 1: PART OF ST. JAGO, ONE OF THE CAPE DE VERDE ISLANDS.)

The island of St. Jago extends in a N.N.W. and S.S.E. direction, thirty miles in length by about twelve in breadth. My observations, made during two visits, were confined to the southern portion within the distance of a few leagues from Porto Praya. The country, viewed from the sea, presents a varied outline: smooth conical hills of a reddish colour (like Red Hill in Figure 1 (Map 1). (The outline of the coast, the position of the villages, streamlets, and of most of the hills in this woodcut, are copied from the chart made on board H.M.S. "Leven." The square-topped hills (A, B, C, etc.) are put in merely by eye, to illustrate my description.)), and others less regular, flat-topped, and of a blackish colour (like A, B, C,) rise from successive, step-formed plains of lava. At a distance, a chain of mountains, many thousand feet in height, traverses the interior of the island. There is no active volcano in St. Jago, and only one in the group, namely at Fogo. The island since being inhabited has not suffered from destructive earthquakes.

The lowest rocks exposed on the coast near Porto Praya, are highly crystalline and compact; they appear to be of ancient, submarine, volcanic origin; they are unconformably covered by a thin, irregular, calcareous deposit, abounding with shells of a late tertiary period; and this again is capped by a wide sheet of basaltic lava, which has flowed in successive streams from the interior of the island, between the square-topped hills marked A, B, C, etc. Still more recent streams of lava have been erupted from the scattered cones, such as Red and Signal Post Hills. The upper strata of the square-topped hills are intimately related in mineralogical composition, and in other respects, with the lowest series of the coast- rocks, with which they seem to be continuous.

MINERALOGICAL DESCRIPTION OF THE ROCKS OF THE LOWEST SERIES.

These rocks possess an extremely varying character; they consist of black, brown, and grey, compact, basaltic bases, with numerous crystals of augite, hornblende, olivine, mica, and sometimes glassy feldspar. A common variety is almost entirely composed of crystals of augite with olivine. Mica, it is known, seldom occurs where augite abounds; nor probably does the present case offer a real exception, for the mica (at least in my best characterised specimen, in which one nodule of this mineral is nearly half an inch in length) is as perfectly rounded as a pebble in a conglomerate, and evidently has not been crystallised in the base, in which it is now enclosed, but has proceeded from the fusion of some pre-existing rock. These compact lavas alternate with tuffs, amygdaloids, and wacke, and in some places with coarse conglomerate. Some of the argillaceous wackes are of a dark green colour, others, pale yellowish-green, and others nearly white; I was surprised to find that some of the latter varieties, even where whitest, fused into a jet black enamel, whilst some of the green varieties afforded only a pale gray bead. Numerous dikes, consisting chiefly of highly compact augitic rocks, and of gray amygdaloidal varieties, intersect the strata, which have in several places been dislocated with considerable violence, and thrown into highly inclined positions. One line of disturbance crosses the northern end of Quail Island (an islet in the Bay of Porto Praya), and can be followed to the mainland. These disturbances took place before the deposition of the recent sedimentary bed; and the surface, also, had previously been denuded to a great extent, as is shown by many truncated dikes.

DESCRIPTION OF THE CALCAREOUS DEPOSIT OVERLYING THE FOREGOING VOLCANIC ROCKS.

This stratum is very conspicuous from its white colour, and from the extreme regularity with which it ranges in a horizontal line for some miles along the coast. Its average height above the sea, measured from the upper line of junction with the superincumbent basaltic lava, is about sixty feet; and its thickness, although varying much from the inequalities of the underlying formation, may be estimated at about twenty feet. It consists of quite white calcareous matter, partly composed of organic debris, and partly of a substance which may be aptly compared in appearance with mortar. Fragments of rock and pebbles are scattered throughout this bed, often forming, especially in the lower part, a conglomerate. Many of the fragments of rock are whitewashed with a thin coating of calcareous matter. At Quail Island, the calcareous deposit is replaced in its lowest part by a soft, brown, earthy tuff, full of Turritellae; this is covered by a bed of pebbles, passing into sandstone, and mixed with fragments of echini, claws of crabs, and shells; the oyster-shells still adhering to the rock on which they grew. Numerous white balls appearing like pisolitic concretions, from the size of a walnut to that of an apple, are embedded in this deposit; they usually have a small pebble in their centres. Although so like concretions, a close examination convinced me that they were Nulliporae, retaining their proper forms, but with their surfaces slightly abraded: these bodies (plants as they are now generally considered to be) exhibit under a microscope of ordinary power, no traces of organisation in their internal structure. Mr. George R. Sowerby has been so good as to examine the shells which I collected: there are fourteen species in a sufficiently perfect condition for their characters to be made out with some degree of certainty, and four which can be referred only to their genera. Of the fourteen shells, of which a list is given in the Appendix, eleven are recent species; one, though undescribed, is perhaps identical with a species which I found living in the harbour of Porto Praya; the two remaining species are unknown, and have been described by Mr. Sowerby. Until the shells of this Archipelago and of the neighbouring coasts are better known, it would be rash to assert that even these two latter shells are extinct. The number of species which certainly belong to existing kinds, although few in number, are sufficient to show that the deposit belongs to a late tertiary period. From its mineralogical character, from the number and size of the embedded fragments, and from the abundance of Patellae, and other littoral shells, it is evident that the whole was accumulated in a shallow sea, near an ancient coast-line.

EFFECTS PRODUCED BY THE FLOWING OF THE SUPERINCUMBENT BASALTIC LAVA OVER THE CALCAREOUS DEPOSIT.

These effects are very curious. The calcareous matter is altered to the depth of about a foot beneath the line of junction; and a most perfect gradation can be traced, from loosely aggregated, small, particles of shells, corallines, and Nulliporae, into a rock, in which not a trace of mechanical origin can be discovered, even with a microscope. Where the metamorphic change has been greatest, two varieties occur. The first is a hard, compact, white, fine-grained rock, striped with a few parallel lines of black volcanic particles, and resembling a sandstone, but which, upon close examination, is seen to be crystallised throughout, with the cleavages so perfect that they can be readily measured by the reflecting goniometer. In specimens, where the change has been less complete, when moistened and examined under a strong lens, the most interesting gradation can be traced, some of the rounded particles retaining their proper forms, and others insensibly melting into the granulo-crystalline paste. The weathered surface of this stone, as is so frequently the case with ordinary limestones, assumes a brick-red colour.

The second metamorphosed variety is likewise a hard rock, but without any crystalline structure. It consists of a white, opaque, compact, calcareous stone, thickly mottled with rounded, though regular, spots of a soft, earthy, ochraceous substance. This earthy matter is of a pale yellowish- brown colour, and appears to be a mixture of carbonate of lime with iron; it effervesces with acids, is infusible, but blackens under the blowpipe, and becomes magnetic. The rounded form of the minute patches of earthy substance, and the steps in the progress of their perfect formation, which can be followed in a suit of specimens, clearly show that they are due either to some power of aggregation in the earthy particles amongst themselves, or more probably to a strong attraction between the atoms of the carbonate of line, and consequently to the segregation of the earthy extraneous matter. I was much interested by this fact, because I have often seen quartz rocks (for instance, in the Falkland Islands, and in the lower Silurian strata of the Stiper-stones in Shropshire), mottled in a precisely analogous manner, with little spots of a white, earthy substance (earthy feldspar?); and these rocks, there was good reason to suppose, had undergone the action of heat,-a view which thus receives confirmation. This spotted structure may possibly afford some indication in distinguishing those formations of quartz, which owe their present structure to igneous action, from those produced by the agency of water alone; a source of doubt, which I should think from my own experience, that most geologists, when examining arenaceo-quartzose districts must have experienced.

The lowest and most scoriaceous part of the lava, in rolling over the sedimentary deposit at the bottom of the sea, has caught up large quantities of calcareous matter, which now forms a snow-white, highly crystalline basis to a breccia, including small pieces of black, glossy scoriae. A little above this, where the lime is less abundant, and the lava more compact, numerous little balls, composed of spicula of calcareous spar, radiating from common centres, occupy the interstices. In one part of Quail Island, the lime has thus been crystallised by the heat of the superincumbent lava, where it is only thirteen feet in thickness; nor had the lava been originally thicker, and since reduced by degradation, as could be told from the degree of cellularity of its surface. I have already observed that the sea must have been shallow in which the calcareous deposit was accumulated. In this case, therefore, the carbonic acid gas has been retained under a pressure, insignificant compared with that (a column of water, 1,708 feet in height) originally supposed by Sir James Hall to be requisite for this end: but since his experiments, it has been discovered that pressure has less to do with the retention of carbonic acid gas, than the nature of the circumjacent atmosphere; and hence, as is stated to be the case by Mr. Faraday, masses of limestone are sometimes fused and crystallised even in common limekilns. (I am much indebted to Mr. E.W. Brayley in having given me the following references to papers on this subject: Faraday in the "Edinburgh New Philosophical Journal" volume 15 page 398; Gay-Lussac in "Annales de Chem. et Phys." tome 63 page 219 translated in the "London and Edinburgh Philosophical Magazine" volume 10 page 496.) Carbonate of lime can be heated to almost any degree, according to Faraday, in an atmosphere of carbonic acid gas, without being decomposed; and Gay-Lussac found that fragments of limestone, placed in a tube and heated to a degree, not sufficient by itself to cause their decomposition, yet immediately evolved their carbonic acid, when a stream of common air or steam was passed over them: Gay-Lussac attributes this to the mechanical displacement of the nascent carbonic acid gas. The calcareous matter beneath the lava, and especially that forming the crystalline spicula between the interstices of the scoriae, although heated in an atmosphere probably composed chiefly of steam, could not have been subjected to the effects of a passing stream; and hence it is, perhaps, that they have retained their carbonic acid, under a small amount of pressure.

The fragments of scoriae, embedded in the crystalline calcareous basis, are of a jet black colour, with a glossy fracture like pitchstone. Their surfaces, however, are coated with a layer of a reddish-orange, translucent substance, which can easily be scratched with a knife; hence they appear as if overlaid by a thin layer of rosin. Some of the smaller fragments are partially changed throughout into this substance: a change which appears quite different from ordinary decomposition. At the Galapagos Archipelago (as will be described in a future chapter), great beds are formed of volcanic ashes and particles of scoriae, which have undergone a closely similar change.

THE EXTENT AND HORIZONTALITY OF THE CALCAREOUS STRATUM.

(FIGURE 2: SIGNAL POST HILL. (Section with A low and C high.)

A.-Ancient volcanic rocks.

B.-Calcareous stratum.

C.-Upper basaltic lava.)

The upper line of surface of the calcareous stratum, which is so conspicuous from being quite white and so nearly horizontal, ranges for miles along the coast, at the height of about sixty feet above the sea. The sheet of basalt, by which it is capped, is on an average eighty feet in thickness. Westward of Porto Praya beyond Red Hill, the white stratum with the superincumbent basalt is covered up by more recent streams. Northward of Signal Post Hill, I could follow it with my eye, trending away for several miles along the sea cliffs. The distance thus observed is about seven miles; but I cannot doubt from its regularity that it extends much farther. In some ravines at right angles to the coast, it is seen gently dipping towards the sea, probably with the same inclination as when deposited round the ancient shores of the island. I found only one inland section, namely, at the base of the hill marked A, where, at the height of some hundred feet, this bed was exposed; it here rested on the usual compact augitic rock associated with wacke, and was covered by the widespread sheet of modern basaltic lava. Some exceptions occur to the horizontality of the white stratum: at Quail Island, its upper surface is only forty feet above the level of the sea; here also the capping of lava is only between twelve and fifteen feet in thickness; on the other hand, at the north-east side of Porto Praya harbour, the calcareous stratum, as well as the rock on which it rests, attain a height above the average level: the inequality of level in these two cases is not, as I believe, owing to unequal elevation, but to original irregularities at the bottom of the sea. Of this fact, at Quail Island, there was clear evidence in the calcareous deposit being in one part of much greater than the average thickness, and in another part being entirely absent; in this latter case, the modern basaltic lavas rested directly on those of more ancient origin.

Under Signal Post Hill, the white stratum dips into the sea in a remarkable manner. This hill is conical, 450 feet in height, and retains some traces of having had a crateriform structure; it is composed chiefly of matter erupted posteriorly to the elevation of the great basaltic plain, but partly of lava of apparently submarine origin and of considerable antiquity. The surrounding plain, as well as the eastern flank of this hill, has been worn into steep precipices, overhanging the sea. In these precipices, the white calcareous stratum may be seen, at the height of about seventy feet above the beach, running for some miles both northward and southward of the hill, in a line appearing to be perfectly horizontal; but for a space of a quarter of a mile directly under the hill, it dips into the sea and disappears. On the south side the dip is gradual, on the north side it is more abrupt, as is shown in Figure 2. As neither the calcareous stratum, nor the superincumbent basaltic lava (as far as the latter can be distinguished from the more modern ejections), appears to thicken as it dips, I infer that these strata were not originally accumulated in a trough, the centre of which afterwards became a point of eruption; but that they have subsequently been disturbed and bent. We may suppose either that Signal Post Hill subsided after its elevation with the surrounding country, or that it never was uplifted to the same height with it. This latter seems to me the most probable alternative, for during the slow and equable elevation of this portion of the island, the subterranean motive power, from expending part of its force in repeatedly erupting volcanic matter from beneath this point, would, it is likely, have less force to uplift it. Something of the same kind seems to have occurred near Red Hill, for when tracing upwards the naked streams of lava from near Porto Praya towards the interior of the island, I was strongly induced to suspect, that since the lava had flowed, the slope of the land had been slightly modified, either by a small subsidence near Red Hill, or by that portion of the plain having been uplifted to a less height during the elevation of the whole area.

THE BASALTIC LAVA, SUPERINCUMBENT ON THE CALCAREOUS DEPOSIT.

This lava is of a pale grey colour, fusing into a black enamel; its fracture is rather earthy and concretionary; it contains olivine in small grains. The central parts of the mass are compact, or at most crenulated with a few minute cavities, and are often columnar. At Quail Island this structure was assumed in a striking manner; the lava in one part being divided into horizontal laminae, which became in another part split by vertical fissures into five-sided plates; and these again, being piled on each other, insensibly became soldered together, forming fine symmetrical columns. The lower surface of the lava is vesicular, but sometimes only to the thickness of a few inches; the upper surface, which is likewise vesicular, is divided into balls, frequently as much as three feet in diameter, made up of concentric layers. The mass is composed of more than one stream; its total thickness being, on an average, about eighty feet: the lower portion has certainly flowed beneath the sea, and probably likewise the upper portion. The chief part of this lava has flowed from the central districts, between the hills marked A, B, C, etc., in the woodcut- map. The surface of the country, near the coast, is level and barren; towards the interior, the land rises by successive terraces, of which four, when viewed from a distance, could be distinctly counted.

VOLCANIC ERUPTIONS SUBSEQUENT TO THE ELEVATION OF THE COASTLAND; THE EJECTED MATTER ASSOCIATED WITH EARTHY LIME.

These recent lavas have proceeded from those scattered, conical, reddish- coloured hills, which rise abruptly from the plain-country near the coast. I ascended some of them, but will describe only one, namely, RED HILL, which may serve as a type of its class, and is remarkable in some especial respects. Its height is about six hundred feet; it is composed of bright red, highly scoriaceous rock of a basaltic nature; on one side of its summit there is a hollow, probably the last remnant of a crater. Several of the other hills of this class, judging from their external forms, are surmounted by much more perfect craters. When sailing along the coast, it was evident that a considerable body of lava had flowed from Red Hill, over a line of cliff about one hundred and twenty feet in height, into the sea: this line of cliff is continuous with that forming the coast, and bounding the plain on both sides of this hill; these streams, therefore, were erupted, after the formation of the coast-cliffs, from Red Hill, when it must have stood, as it now does, above the level of the sea. This conclusion accords with the highly scoriaceous condition of all the rock on it, appearing to be of subaerial formation: and this is important, as there are some beds of calcareous matter near its summit, which might, at a hasty glance, have been mistaken for a submarine deposit. These beds consist of white, earthy, carbonate of lime, extremely friable so as to be crushed with the least pressure; the most compact specimens not resisting the strength of the fingers. Some of the masses are as white as quicklime, and appear absolutely pure; but on examining them with a lens, minute particles of scoriae can always be seen, and I could find none which, when dissolved in acids, did not leave a residue of this nature. It is, moreover, difficult to find a particle of the lime which does not change colour under the blowpipe, most of them even becoming glazed. The scoriaceous fragments and the calcareous matter are associated in the most irregular manner, sometimes in obscure beds, but more generally as a confused breccia, the lime in some parts and the scoriae in others being most abundant. Sir H. De la Beche has been so kind as to have some of the purest specimens analysed, with a view to discover, considering their volcanic origin, whether they contained much magnesia; but only a small portion was found, such as is present in most limestones.

Fragments of the scoriae embedded in the calcareous mass, when broken, exhibit many of their cells lined and partly filled with a white, delicate, excessively fragile, moss-like, or rather conferva-like, reticulation of carbonate of lime. These fibres, examined under a lens of one-tenth of an inch focal distance, appear cylindrical; they are rather above one- thousandth of an inch in diameter; they are either simply branched, or more commonly united into an irregular mass of network, with the meshes of very unequal sizes and of unequal numbers of sides. Some of the fibres are thickly covered with extremely minute spicula, occasionally aggregated into little tuffs; and hence they have a hairy appearance. These spicula are of the same diameter throughout their length; they are easily detached, so that the object-glass of the microscope soon becomes scattered over with them. Within the cells of many fragments of the scoria, the lime exhibits this fibrous structure, but generally in a less perfect degree. These cells do not appear to be connected with one another. There can be no doubt, as will presently be shown, that the lime was erupted, mingled with the lava in its fluid state, and therefore I have thought it worth while to describe minutely this curious fibrous structure, of which I know nothing analogous. From the earthy condition of the fibres, this structure does not appear to be related to crystallisation.

Other fragments of the scoriaceous rock from this hill, when broken, are often seen marked with short and irregular white streaks, which are owing to a row of separate cells being partly, or quite, filled with white calcareous powder. This structure immediately reminded me of the appearance in badly kneaded dough, of balls and drawn-out streaks of flour, which have remained unmixed with the paste; and I cannot doubt that small masses of the lime, in the same manner remaining unmixed with the fluid lava, have been drawn out when the whole was in motion. I carefully examined, by trituration and solution in acids, pieces of the scoriae, taken from within half-an-inch of those cells which were filled with the calcareous powder, and they did not contain an atom of free lime. It is obvious that the lava and lime have on a large scale been very imperfectly mingled; and where small portions of the lime have been entangled within a piece of the viscid lava, the cause of their now occupying, in the form of a powder or of a fibrous reticulation, the vesicular cavities, is, I think, evidently due to the confined gases having most readily expanded at the points where the incoherent lime rendered the lava less adhesive.

A mile eastward of the town of Praya, there is a steep-sided gorge, about one hundred and fifty yards in width, cutting through the basaltic plain and underlying beds, but since filled up by a stream of more modern lava. This lava is dark grey, and in most parts compact and rudely columnar; but at a little distance from the coast, it includes in an irregular manner a brecciated mass of red scoriae mingled with a considerable quantity of white, friable, and in some parts, nearly pure earthy lime, like that on the summit of Red Hill. This lava, with its entangled lime, has certainly flowed in the form of a regular stream; and, judging from the shape of the gorge, towards which the drainage of the country (feeble though it now be) still is directed, and from the appearance of the bed of loose water-worn blocks with their interstices unfilled, like those in the bed of a torrent, on which the lava rests, we may conclude that the stream was of subaerial origin. I was unable to trace it to its source, but, from its direction, it seemed to have come from Signal Post Hill, distant one mile and a quarter, which, like Red Hill, has been a point of eruption subsequent to the elevation of the great basaltic plain. It accords with this view, that I found on Signal Post Hill, a mass of earthy, calcareous matter of the same nature, mingled with scoriae. I may here observe that part of the calcareous matter forming the horizontal sedimentary bed, especially the finer matter with which the embedded fragments of rock are whitewashed, has probably been derived from similar volcanic eruptions, as well as from triturated organic remains: the underlying, ancient, crystalline rocks, also, are associated with much carbonate of lime, filling amygdaloidal cavities, and forming irregular masses, the nature of which latter I was unable to understand.

Considering the abundance of earthy lime near the summit of Red Hill, a volcanic cone six hundred feet in height, of subaerial growth,-considering the intimate manner in which minute particles and large masses of scoriae are embedded in the masses of nearly pure lime, and on the other hand, the manner in which small kernels and streaks of the calcareous powder are included in solid pieces of the scoriae,-considering, also, the similar occurrence of lime and scoriae within a stream of lava, also supposed, with good reason, to have been of modern subaerial origin, and to have flowed from a hill, where earthy lime also occurs: I think, considering these facts, there can be no doubt that the lime has been erupted, mingled with the molten lava. I am not aware that any similar case has been described: it appears to me an interesting one, inasmuch as most geologists must have speculated on the probable effects of a volcanic focus, bursting through deep-seated beds of different mineralogical composition. The great abundance of free silex in the trachytes of some countries (as described by Beudant in Hungary, and by P. Scrope in the Panza Islands), perhaps solves the inquiry with respect to deep-seated beds of quartz; and we probably here see it answered, where the volcanic action has invaded subjacent masses of limestone. One is naturally led to conjecture in what state the now earthy carbonate of lime existed, when ejected with the intensely heated lava: from the extreme cellularity of the scoriae on Red Hill, the pressure cannot have been great, and as most volcanic eruptions are accompanied by the emission of large quantities of steam and other gases, we here have the most favourable conditions, according to the views at present entertained by chemists, for the expulsion of the carbonic acid. (Whilst deep beneath the surface, the carbonate of lime was, I presume, in a fluid state. Hutton, it is known, thought that all amygdaloids were produced by drops of molten limestone floating in the trap, like oil in water: this no doubt is erroneous, but if the matter forming the summit of Red Hill had been cooled under the pressure of a moderately deep sea, or within the walls of a dike, we should, in all probability, have had a trap rock associated with large masses of compact, crystalline, calcareous spar, which, according to the views entertained by many geologists, would have been wrongly attributed to subsequent infiltration.) Has the slow re- absorption of this gas, it may be asked, given to the lime in the cells of the lava, that peculiar fibrous structure, like that of an efflorescing salt? Finally, I may remark on the great contrast in appearance between this earthy lime, which must have been heated in a free atmosphere of steam and other gases, while the white, crystalline, calcareous spar, produced by a single thin sheet of lava (as at Quail Island) rolling over similar earthy lime and the debris of organic remains, at the bottom of a shallow sea.

SIGNAL POST HILL.

This hill has already been several times mentioned, especially with reference to the remarkable manner in which the white calcareous stratum, in other parts so horizontal (Figure 2), dips under it into the sea. It has a broad summit, with obscure traces of a crateriform structure, and is composed of basaltic rocks (Of these, one common variety is remarkable for being full of small fragments of a dark jasper-red earthy mineral, which, when examined carefully, shows an indistinct cleavage; the little fragments are elongated in form, are soft, are magnetic before and after being heated, and fuse with difficulty into a dull enamel. This mineral is evidently closely related to the oxides of iron, but I cannot ascertain what it exactly is. The rock containing this mineral is crenulated with small angular cavities, which are lined and filled with yellowish crystals of carbonate of lime.), some compact, others highly cellular with inclined beds of loose scoriae, of which some are associated with earthy lime. Like Red Hill, it has been the source of eruptions, subsequently to the elevation of the surrounding basaltic plain; but unlike that hill, it has undergone considerable denudation, and has been the seat of volcanic action at a remote period, when beneath the sea. I judge of this latter circumstance from finding on its inland flank the last remains of three small points of eruption. These points are composed of glossy scoriae, cemented by crystalline calcareous spar, exactly like the great submarine calcareous deposit, where the heated lava has rolled over it: their demolished state can, I think, be explained only by the denuding action of the waves of the sea. I was guided to the first orifice by observing a sheet of lava, about two hundred yards square, with steepish sides, superimposed on the basaltic plain with no adjoining hillock, whence it could have been erupted; and the only trace of a crater which I was able to discover, consisted of some inclined beds of scoriae at one of its corners. At the distance of fifty yards from a second level-topped patch of lava, but of much smaller size, I found an irregular circular group of masses of cemented, scoriaceous breccia, about six feet in height, which doubtless had once formed the point of eruption. The third orifice is now marked only by an irregular circle of cemented scoriae, about four yards in diameter, and rising in its highest point scarcely three feet above the level of the plain, the surface of which, close all round, exhibits its usual appearance: here we have a horizontal basal section of a volcanic spiracle, which, together with all its ejected matter, has been almost totally obliterated.

The stream of lava, which fills the narrow gorge eastward of the town of Praya, judging from its course, seems, as before remarked, to have come from Signal Post Hill, and to have flowed over the plain, after its elevation (The sides of this gorge, where the upper basaltic stratum is intersected, are almost perpendicular. The lava, which has since filled it up, is attached to these sides, almost as firmly as a dike is to its walls. In most cases, where a stream of lava has flowed down a valley, it is bounded on each side by loose scoriaceous masses.): the same observation applies to a stream (possibly part of the same one) capping the sea cliffs, a little eastward of the gorge. When I endeavoured to follow these streams over the stony level plain, which is almost destitute of soil and vegetation, I was much surprised to find, that although composed of hard basaltic matter, and not having been exposed to marine denudation, all distant traces of them soon became utterly lost. But I have since observed at the Galapagos Archipelago, that it is often impossible to follow even great deluges of quite recent lava across older streams, except by the size of the bushes growing on them, or by the comparative states of glossiness of their surfaces,-characters which a short lapse of time would be sufficient quite to obscure. I may remark, that in a level country, with a dry climate, and with the wind blowing always in one direction (as at the Cape de Verde Archipelago), the effects of atmospheric degradation are probably much greater than would at first be expected; for soil in this case accumulates only in a few protected hollows, and being blown in one direction, it is always travelling towards the sea in the form of the finest dust, leaving the surface of the rocks bare, and exposed to the full effects of renewed meteoric action.

INLAND HILLS OF MORE ANCIENT VOLCANIC ROCKS.

These hills are laid down by eye, and marked as A, B, C, etc., in Map 1. They are related in mineralogical composition, and are probably directly continuous with the lowest rocks exposed on the coast. These hills, viewed from a distance, appear as if they had once formed part of an irregular tableland, and from their corresponding structure and composition this probably has been the case. They have flat, slightly inclined summits, and are, on an average, about six hundred feet in height; they present their steepest slope towards the interior of the island, from which point they radiate outwards, and are separated from each other by broad and deep valleys, through which the great streams of lava, forming the coast-plains, have descended. Their inner and steeper escarpments are ranged in an irregular curve, which rudely follows the line of the shore, two or three miles inland from it. I ascended a few of these hills, and from others, which I was able to examine with a telescope, I obtained specimens, through the kindness of Mr. Kent, the assistant-surgeon of the "Beagle"; although by these means I am acquainted with only a part of the range, five or six miles in length, yet I scarcely hesitate, from their uniform structure, to affirm that they are parts of one great formation, stretching round much of the circumference of the island.

The upper and lower strata of these hills differ greatly in composition. The upper are basaltic, generally compact, but sometimes scoriaceous and amygdaloidal, with associated masses of wacke: where the basalt is compact, it is either fine-grained or very coarsely crystallised; in the latter case it passes into an augitic rock, containing much olivine; the olivine is either colourless, or of the usual yellow and dull reddish shades. On some of the hills, beds of calcareous matter, both in an earthy and in a crystalline form, including fragments of glossy scoriae, are associated with the basaltic strata. These strata differ from the streams of basaltic lava forming the coast-plains, only in being more compact, and in the crystals of augite, and in the grains of olivine being of much greater size;-characters which, together with the appearance of the associated calcareous beds, induce me to believe that they are of submarine formation.

Some considerable masses of wacke, which are associated with these basaltic strata, and which likewise occur in the basal series on the coast, especially at Quail Island, are curious. They consist of a pale yellowish- green argillaceous substance, of a crumbling texture when dry, but unctuous when moist: in its purest form, it is of a beautiful green tint, with translucent edges, and occasionally with obscure traces of an original cleavage. Under the blowpipe it fuses very readily into a dark grey, and sometimes even black bead, which is slightly magnetic. From these characters, I naturally thought that it was one of the pale species, decomposed, of the genus augite;-a conclusion supported by the unaltered rock being full of large separate crystals of black augite, and of balls and irregular streaks of dark grey augitic rock. As the basalt ordinarily consists of augite, and of olivine often tarnished and of a dull red colour, I was led to examine the stages of decomposition of this latter mineral, and I found, to my surprise, that I could trace a nearly perfect gradation from unaltered olivine to the green wacke. Part of the same grain under the blowpipe would in some instances behave like olivine, its colour being only slightly changed, and part would give a black magnetic bead. Hence I can have no doubt that the greenish wacke originally existed as olivine; but great chemical changes must have been effected during the act of decomposition thus to have altered a very hard, transparent, infusible mineral, into a soft, unctuous, easily melted, argillaceous substance. (D'Aubuisson "Traite de Geognosie" tome 2 page 569 mentions, on the authority of M. Marcel de Serres, masses of green earth near Montpellier, which are supposed to be due to the decomposition of olivine. I do not, however, find, that the action of this mineral under the blowpipe being entirely altered, as it becomes decomposed, has been noticed; and the knowledge of this fact is important, as at first it appears highly improbable that a hard, transparent, refractory mineral should be changed into a soft, easily fused clay, like this of St. Jago. I shall hereafter describe a green substance, forming threads within the cells of some vesicular basaltic rocks in Van Diemen's Land, which behave under the blowpipe like the green wacke of St. Jago; but its occurrence in cylindrical threads, shows it cannot have resulted from the decomposition of olivine, a mineral always existing in the form of grains or crystals.)

The basal strata of these hills, as well as some neighbouring, separate, bare, rounded hillocks, consist of compact, fine-grained, non-crystalline (or so slightly as scarcely to be perceptible), ferruginous, feldspathic rocks, and generally in a state of semi-decomposition. Their fracture is exceedingly irregular, and splintery; yet small fragments are often very tough. They contain much ferruginous matter, either in the form of minute grains with a metallic lustre, or of brown hair-like threads: the rock in this latter case assuming a pseudo-brecciated structure. These rocks sometimes contain mica and veins of agate. Their rusty brown or yellowish colour is partly due to the oxides of iron, but chiefly to innumerable, microscopically minute, black specks, which, when a fragment is heated, are easily fused, and evidently are either hornblende or augite. These rocks, therefore, although at first appearing like baked clay or some altered sedimentary deposit, contain all the essential ingredients of trachyte; from which they differ only in not being harsh, and in not containing crystals of glassy feldspar. As is so often the case with trachytic formation, no stratification is here apparent. A person would not readily believe that these rocks could have flowed as lava; yet at St. Helena there are well-characterised streams (as will be described in an ensuing chapter) of nearly similar composition. Amidst the hillocks composed of these rocks, I found in three places, smooth conical hills of phonolite, abounding with fine crystals of glassy feldspar, and with needles of hornblende. These cones of phonolite, I believe, bear the same relation to the surrounding feldspathic strata which some masses of coarsely crystallised augitic rock, in another part of the island, bear to the surrounding basalt, namely, that both have been injected. The rocks of a feldspathic nature being anterior in origin to the basaltic strata, which cap them, as well as to the basaltic streams of the coast-plains, accords with the usual order of succession of these two grand divisions of the volcanic series.

The strata of most of these hills in the upper part, where alone the planes of division are distinguishable, are inclined at a small angle from the interior of the island towards the sea-coast. The inclination is not the same in each hill; in that marked A it is less than in B, D, or E; in C the strata are scarcely deflected from a horizontal plane, and in F (as far as I could judge without ascending it) they are slightly inclined in a reverse direction, that is, inwards and towards the centre of the island. Notwithstanding these differences of inclination, their correspondence in external form, and in the composition both of their upper and lower parts,- -their relative position in one curved line, with their steepest sides turned inwards,-all seem to show that they originally formed parts of one platform; which platform, as before remarked, probably extended round a considerable portion of the circumference of the island. The upper strata certainly flowed as lava, and probably beneath the sea, as perhaps did the lower feldspathic masses: how then come these strata to hold their present position, and whence were they erupted?

In the centre of the island there are lofty mountains, but they are separated from the steep inland flanks of these hills by a wide space of lower country: the interior mountains, moreover, seem to have been the source of those great streams of basaltic lava which, contracting as they pass between the bases of the hills in question, expand into the coast- plains. (I saw very little of the inland parts of the island. Near the village of St. Domingo, there are magnificent cliffs of rather coarsely crystallised basaltic lava. Following the little stream in this valley, about a mile above the village, the base of the great cliff was formed of a compact fine-grained basalt, conformably covered by a bed of pebbles. Near Fuentes, I met with pap-formed hills of the compact feldspathic series of rocks.) Round the shores of St. Helena there is a rudely formed ring of basaltic rocks, and at Mauritius there are remnants of another such a ring round part, if not round the whole, of the island; here again the same question immediately occurs, how came these masses to hold their present position, and whence were they erupted? The same answer, whatever it may be, probably applies in these three cases; and in a future chapter we shall recur to this subject.

VALLEYS NEAR THE COAST.

These are broad, very flat, and generally bounded by low cliff-formed sides. Portions of the basaltic plain are sometimes nearly or quite isolated by them; of which fact, the space on which the town of Praya stands offers an instance. The great valley west of the town has its bottom filled up to a depth of more than twenty feet by well-rounded pebbles, which in some parts are firmly cemented together by white calcareous matter. There can be no doubt, from the form of these valleys, that they were scooped out by the waves of the sea, during that equable elevation of the land, of which the horizontal calcareous deposit, with its existing species of marine remains, gives evidence. Considering how well shells have been preserved in this stratum, it is singular that I could not find even a single small fragment of shell in the conglomerate at the bottom of the valleys. The bed of pebbles in the valley west of the town is intersected by a second valley joining it as a tributary, but even this valley appears much too wide and flat-bottomed to have been formed by the small quantity of water, which falls only during one short wet season; for at other times of the year these valleys are absolutely dry.

RECENT CONGLOMERATE.

On the shores of Quail Island, I found fragments of brick, bolts of iron, pebbles, and large fragments of basalt, united by a scanty base of impure calcareous matter into a firm conglomerate. To show how exceedingly firm this recent conglomerate is, I may mention, that I endeavoured with a heavy geological hammer to knock out a thick bolt of iron, which was embedded a little above low-water mark, but was quite unable to succeed.

FERNANDO NORONHA.

Precipitous hill of phonolite.

TERCEIRA.

Trachytic rocks: their singular decomposition by steam of high temperature.

TAHITI. Passage from wacke into trap; singular volcanic rock with the vesicles half-filled with mesotype.

MAURITIUS.

Proofs of its recent elevation.

Structure of its more ancient mountains; similarity with St. Jago.

ST. PAUL'S ROCKS.

Not of volcanic origin.

Their singular mineralogical composition.

FERNANDO NORONHA.

During our short visit at this and the four following islands, I observed very little worthy of description. Fernando Noronha is situated in the Atlantic Ocean, in latitude 3 degrees 50 minutes S., and 230 miles distant from the coast of South America. It consists of several islets, together nine miles in length by three in breadth. The whole seems to be of volcanic origin; although there is no appearance of any crater, or of any one central eminence. The most remarkable feature is a hill 1,000 feet high, of which the upper 400 feet consist of a precipitous, singularly shaped pinnacle, formed of columnar phonolite, containing numerous crystals of glassy feldspar, and a few needles of hornblende. From the highest accessible point of this hill, I could distinguish in different parts of the group several other conical hills, apparently of the same nature. At St. Helena there are similar, great, conical, protuberant masses of phonolite, nearly one thousand feet in height, which have been formed by the injection of fluid feldspathic lava into yielding strata. If this hill has had, as is probable, a similar origin, denudation has been here effected on an enormous scale. Near the base of this hill, I observed beds of white tuff, intersected by numerous dikes, some of amygdaloidal basalt and others of trachyte; and beds of slaty phonolite with the planes of cleavage directed N.W. and S.E. Parts of this rock, where the crystals were scanty, closely resembled common clay-slate, altered by the contact of a trap-dike. The lamination of rocks, which undoubtedly have once been fluid, appears to me a subject well deserving attention. On the beach there were numerous fragments of compact basalt, of which rock a distant facade of columns seemed to be formed.

TERCEIRA IN THE AZORES.

The central parts of this island consist of irregularly rounded mountains of no great elevation, composed of trachyte, which closely resembles in general character the trachyte of Ascension, presently to be described. This formation is in many parts overlaid, in the usual order of superposition, by streams of basaltic lava, which near the coast compose nearly the whole surface. The course which these streams have followed from their craters, can often be followed by the eye. The town of Angra is overlooked by a crateriform hill (Mount Brazil), entirely built of thin strata of fine-grained, harsh, brown-coloured tuff. The upper beds are seen to overlap the basaltic streams on which the town stands. This hill is almost identical in structure and composition with numerous crateriformed hills in the Galapagos Archipelago.

EFFECTS OF STEAM ON THE TRACHYTIC ROCKS.

In the central part of the island there is a spot, where steam is constantly issuing in jets from the bottom of a small ravine-like hollow, which has no exit, and which abuts against a range of trachytic mountains. The steam is emitted from several irregular fissures: it is scentless, soon blackens iron, and is of much too high temperature to be endured by the hand. The manner in which the solid trachyte is changed on the borders of these orifices is curious: first, the base becomes earthy, with red freckles evidently due to the oxidation of particles of iron; then it becomes soft; and lastly, even the crystals of glassy feldspar yield to the dissolving agent. After the mass is converted into clay, the oxide of iron seems to be entirely removed from some parts, which are left perfectly white, whilst in other neighbouring parts, which are of the brightest red colour, it seems to be deposited in greater quantity; some other masses are marbled with two distinct colours. Portions of the white clay, now that they are dry, cannot be distinguished by the eye from the finest prepared chalk; and when placed between the teeth they feel equally soft-grained; the inhabitants use this substance for white-washing their houses. The cause of the iron being dissolved in one part, and close by being again deposited, is obscure; but the fact has been observed in several other places. (Spallanzani, Dolomieu, and Hoffman have described similar cases in the Italian volcanic islands. Dolomieu says the iron at the Panza Islands is redeposited in the form of veins (page 86 "Memoire sur les Isles Ponces"). These authors likewise believe that the steam deposits silica: it is now experimentally known that vapour of a high temperature is able to dissolve silica.) In some half-decayed specimens, I found small, globular aggregations of yellow hyalite, resembling gum-arabic, which no doubt had been deposited by the steam.

As there is no escape for the rain-water, which trickles down the sides of the ravine-like hollow, whence the steam issues, it must all percolate downwards through the fissures at its bottom. Some of the inhabitants informed me that it was on record that flames (some luminous appearance?) had originally proceeded from these cracks, and that the flames had been succeeded by the steam; but I was not able to ascertain how long this was ago, or anything certain on the subject. When viewing the spot, I imagined that the injection of a large mass of rock. like the cone of phonolite at Fernando Noronha, in a semi-fluid state, by arching the surface might have caused a wedge-shaped hollow with cracks at the bottom, and that the rain- water percolating to the neighbourhood of the heated mass, would during many succeeding years be driven back in the form of steam.

TAHITI (OTAHEITE).

I visited only a part of the north-western side of this island, and this part is entirely composed of volcanic rocks. Near the coast there are several varieties of basalt, some abounding with large crystals of augite and tarnished olivine, others compact and earthy,-some slightly vesicular, and others occasionally amygdaloidal. These rocks are generally much decomposed, and to my surprise, I found in several sections that it was impossible to distinguish, even approximately, the line of separation between the decayed lava and the alternating beds of tuff. Since the specimens have become dry, it is rather more easy to distinguish the decomposed igneous rocks from the sedimentary tuffs. This gradation in character between rocks having such widely different origins, may I think be explained by the yielding under pressure of the softened sides of the vesicular cavities, which in many volcanic rocks occupy a large proportion of their bulk. As the vesicles generally increase in size and number in the upper parts of a stream of lava, so would the effects of their compression increase; the yielding, moreover, of each lower vesicle must tend to disturb all the softened matter above it. Hence we might expect to trace a perfect gradation from an unaltered crystalline rock to one in which all the particles (although originally forming part of the same solid mass) had undergone mechanical displacement; and such particles could hardly be distinguished from others of similar composition, which had been deposited as sediment. As lavas are sometimes laminated in their upper parts even horizontal lines, appearing like those of aqueous deposition, could not in all cases be relied on as a criterion of sedimentary origin. From these considerations it is not surprising that formerly many geologists believed in real transitions from aqueous deposits, through wacke, into igneous traps.

In the valley of Tia-auru, the commonest rocks are basalts with much olivine, and in some cases almost composed of large crystals of augite. I picked up some specimens, with much glassy feldspar, approaching in character to trachyte. There were also many large blocks of vesicular basalt, with the cavities beautifully lined with chabasie (?), and radiating bundles of mesotype. Some of these specimens presented a curious appearance, owing to a number of the vesicles being half filled up with a white, soft, earthy mesotypic mineral, which intumesced under the blowpipe in a remarkable manner. As the upper surfaces in all the half-filled cells are exactly parallel, it is evident that this substance has sunk to the bottom of each cell from its weight. Sometimes, however, it entirely fills the cells. Other cells are either quite filled, or lined, with small crystals, apparently of chabasie; these crystals, also, frequently line the upper half of the cells partly filled with the earthy mineral, as well as the upper surface of this substance itself, in which case the two minerals appear to blend into each other. I have never seen any other amygdaloid with the cells half filled in the manner here described; and it is difficult to imagine the causes which determined the earthy mineral to sink from its gravity to the bottom of the cells, and the crystalline mineral to adhere in a coating of equal thickness round the sides of the cells. (MacCulloch, however, has described and given a plate of ("Geolog. Trans." 1st series volume 4 page 225) a trap rock, with cavities filled up horizontally with quartz and chalcedony. The upper halves of these cavities are often filled by layers, which follow each irregularity of the surface, and by little depending stalactites of the same siliceous substances.)

The basic strata on the sides of the valley are gently inclined seaward, and I nowhere observed any sign of disturbance; the strata are separated from each other by thick, compact beds of conglomerate, in which the fragments are large, some being rounded, but most angular. From the character of these beds, from the compact and crystalline condition of most of the lavas, and from the nature of the infiltrated minerals, I was led to conjecture that they had originally flowed beneath the sea. This conclusion agrees with the fact that the Rev. W. Ellis found marine remains at a considerable height, which he believes were interstratified with volcanic matter; as is likewise described to be the case by Messrs. Tyerman and Bennett at Huaheine, an island in this same archipelago. Mr. Stutchbury also discovered near the summit of one of the loftiest mountains of Tahiti, at the height of several thousand feet, a stratum of semi-fossil coral. None of these remains have been specifically examined. On the coast, where masses of coral-rock would have afforded the clearest evidence, I looked in vain for any signs of recent elevation. For references to the above authorities, and for more detailed reasons for not believing that Tahiti has been recently elevated, I must refer to the "Structure and Distribution of Coral-Reefs."

MAURITIUS.

Approaching this island on the northern or north-western side, a curved chain of bold mountains, surmounted by rugged pinnacles, is seen to rise from a smooth border of cultivated land, which gently slopes down to the coast. At the first glance, one is tempted to believe that the sea lately reached the base of these mountains, and upon examination, this view, at least with respect to the inferior parts of the border, is found to be perfectly correct. Several authors have described masses of upraised coral- rock round the greater part of the circumference of the island. (Captain Carmichael, in Hooker's "Bot. Misc." volume 2 page 301. Captain Lloyd has lately, in the "Proceedings of the Geological Society" (volume 3 page 317), described carefully some of these masses. In the "Voyage a l'Isle de France, par un Officier du Roi," many interesting facts are given on this subject. Consult also "Voyage aux Quatre Isles d'Afrique, par M. Bory St. Vincent.") Between Tamarin Bay and the Great Black River I observed, in company with Captain Lloyd, two hillocks of coral-rock, formed in their lower part of hard calcareous sandstone, and in their upper of great blocks, slightly aggregated, of Astraea and Madrepora, and of fragments of basalt; they were divided into beds dipping seaward, in one case at an angle of 8 degrees, and in the other at 18 degrees; they had a water-worn appearance, and they rose abruptly from a smooth surface, strewed with rolled debris of organic remains, to a height of about twenty feet. The Officier du Roi, in his most interesting tour in 1768 round the island, has described masses of upraised coral-rocks, still retaining that moat-like structure (see my "Coral Reefs") which is characteristic of the living reefs. On the coast northward of Port Louis, I found the lava concealed for a considerable space inland by a conglomerate of corals and shells, like those on the beach, but in parts consolidated by red ferruginous matter. M. Bory St. Vincent has described similar calcareous beds over nearly the whole of the plain of Pamplemousses. Near Port Louis, when turning over some large stones, which lay in the bed of a stream at the head of a protected creek, and at the height of some yards above the level of spring tides, I found several shells of serpula still adhering to their under sides.

The jagged mountains near Port Louis rise to a height of between two and three thousand feet; they consist of strata of basalt, obscurely separated from each other by firmly aggregated beds of fragmentary matter; and they are intersected by a few vertical dikes. The basalt in some parts abounds with large crystals of augite and olivine, and is generally compact. The interior of the island forms a plain, raised probably about a thousand feet above the level of the sea, and composed of streams of lava which have flowed round and between the rugged basaltic mountains. These more recent lavas are also basaltic, but less compact, and some of them abound with feldspar, so that they even fuse into a pale coloured glass. On the banks of the Great River, a section is exposed nearly five hundred feet deep, worn through numerous thin sheets of the lava of this series, which are separated from each other by beds of scoriae. They seem to have been of subaerial formation, and to have flowed from several points of eruption on the central platform, of which the Piton du Milieu is said to be the principal one. There are also several volcanic cones, apparently of this modern period, round the circumference of the island, especially at the northern end, where they form separate islets.

The mountains composed of the more compact and crystalline basalt, form the main skeleton of the island. M. Bailly ("Voyage aux Terres Australes" tome 1 page 54.) states that they all "se developpent autour d'elle comme une ceinture d'immenses remparts, toutes affectant une pente plus ou moins enclinee vers le rivage de la mer; tandis, au contraire, que vers le centre de l'ile elles presentent une coupe abrupte, et souvent taillee a pic. Toutes ces montagnes sont formees de couches paralleles inclinees du centre de l'ile vers la mer." These statements have been disputed, though not in detail, by M. Quoy, in the voyage of Freycinet. As far as my limited means of observation went, I found them perfectly correct. (M. Lesson, in his account of this island, in the "Voyage of the 'Coquille'," seems to follow M. Bailly's views.) The mountains on the N.W. side of the island, which I examined, namely, La Pouce, Peter Botts, Corps de Garde, Les Mamelles, and apparently another farther southward, have precisely the external shape and stratification described by M. Bailly. They form about a quarter of his girdle of ramparts. Although these mountains now stand quite detached, being separated from each other by breaches, even several miles in width, through which deluges of lava have flowed from the interior of the island; nevertheless, seeing their close general similarity, one must feel convinced that they originally formed parts of one continuous mass. Judging from the beautiful map of the Mauritius, published by the Admiralty from a French MS., there is a range of mountains (M. Bamboo) on the opposite side of the island, which correspond in height, relative position, and external form, with those just described. Whether the girdle was ever complete may well be doubted; but from M. Bailly's statements, and my own observations, it may be safely concluded that mountains with precipitous inland flanks, and composed of strata dipping outwards, once extended round a considerable portion of the circumference of the island. The ring appears to have been oval and of vast size; its shorter axis, measured across from the inner sides of the mountains near Port Louis and those near Grand Port, being no less than thirteen geographical miles in length. M. Bailly boldly supposes that this enormous gulf, which has since been filled up to a great extent by streams of modern lava, was formed by the sinking in of the whole upper part of one great volcano.

It is singular in how many respects those portions of St. Jago and of Mauritius which I visited agree in their geological history. At both islands, mountains of similar external form, stratification, and (at least in their upper beds) composition, follow in a curved chain the coast-line. These mountains in each case appear originally to have formed parts of one continuous mass. The basaltic strata of which they are composed, from their compact and crystalline structure, seem, when contrasted with the neighbouring basaltic streams of subaerial formation, to have flowed beneath the pressure of the sea, and to have been subsequently elevated. We may suppose that the wide breaches between the mountains were in both cases worn by the waves, during their gradual elevation-of which process, within recent times, there is abundant evidence on the coast-land of both islands. At both, vast streams of more recent basaltic lavas have flowed from the interior of the island, round and between the ancient basaltic hills; at both, moreover, recent cones of eruption are scattered around the circumference of the island; but at neither have eruptions taken place within the period of history. As remarked in the last chapter, it is probable that these ancient basaltic mountains, which resemble (at least in many respects) the basal and disturbed remnants of two gigantic volcanoes, owe their present form, structure, and position, to the action of similar causes.

ST. PAUL'S ROCKS.

This small island is situated in the Atlantic Ocean, nearly one degree north of the equator, and 540 miles distant from South America, in 29 degrees 15 minutes west longitude. Its highest point is scarcely fifty feet above the level of the sea; its outline is irregular, and its entire circumference barely three-quarters of a mile. This little point of rock rises abruptly out of the ocean; and, except on its western side, soundings were not obtained, even at the short distance of a quarter of a mile from its shore. It is not of volcanic origin; and this circumstance, which is the most remarkable point in its history (as will hereafter be referred to), properly ought to exclude it from the present volume. It is composed of rocks, unlike any which I have met with, and which I cannot characterise by any name, and must therefore describe.

The simplest, and one of the most abundant kinds, is a very compact, heavy, greenish-black rock, having an angular, irregular fracture, with some points just hard enough to scratch glass, and infusible. This variety passes into others of paler green tints, less hard, but with a more crystalline fracture, and translucent on their edges; and these are fusible into a green enamel. Several other varieties are chiefly characterised by containing innumerable threads of dark-green serpentine, and by having calcareous matter in their interstices. These rocks have an obscure, concretionary structure, and are full of variously coloured angular pseudo fragments. These angular pseudo fragments consist of the first-described dark green rock, of a brown softer kind, of serpentine, and of a yellowish harsh stone, which, perhaps, is related to serpentine rock. There are other vesicular, calcareo-ferruginous, soft stones. There is no distinct stratification, but parts are imperfectly laminated; and the whole abounds with innumerable veins, and vein-like masses, both small and large. Of these vein-like masses, some calcareous ones, which contain minute fragments of shells, are clearly of subsequent origin to the others.

A GLOSSY INCRUSTATION.

Extensive portions of these rocks are coated by a layer of a glossy polished substance, with a pearly lustre and of a greyish white colour; it follows all the inequalities of the surface, to which it is firmly attached. When examined with a lens, it is found to consist of numerous exceedingly thin layers, their aggregate thickness being about the tenth of an inch. It is considerably harder than calcareous spar, but can be scratched with a knife; under the blowpipe it scales off, decrepitates, slightly blackens, emits a fetid odour, and becomes strongly alkaline: it does not effervesce in acids. (In my "Journal" I have described this substance; I then believed that it was an impure phosphate of lime.) I presume this substance has been deposited by water draining from the birds' dung, with which the rocks are covered. At Ascension, near a cavity in the rocks which was filled with a laminated mass of infiltrated birds' dung, I found some irregularly formed, stalactitical masses of apparently the same nature. These masses, when broken, had an earthy texture; but on their outsides, and especially at their extremities, they were formed of a pearly substance, generally in little globules, like the enamel of teeth, but more translucent, and so hard as just to scratch plate-glass. This substance slightly blackens under the blowpipe, emits a bad smell, then becomes quite white, swelling a little, and fuses into a dull white enamel; it does not become alkaline; nor does it effervesce in acids. The whole mass had a collapsed appearance, as if in the formation of the hard glossy crust the whole had shrunk much. At the Abrolhos Islands on the coast of Brazil, where also there is much birds' dung, I found a great quantity of a brown, arborescent substance adhering to some trap-rock. In its arborescent form, this substance singularly resembles some of the branched species of Nullipora. Under the blowpipe, it behaves like the specimens from Ascension; but it is less hard and glossy, and the surface has not the shrunk appearance.

Basaltic lavas.

Numerous craters truncated on the same side.

Singular structure of volcanic bombs.

Aeriform explosions.

Ejected granitic fragments.

Trachytic rocks.

Singular veins.

Jasper, its manner of formation.

Concretions in pumiceous tuff.

Calcareous deposits and frondescent incrustations on the coast.

Remarkable laminated beds, alternating with, and passing into, obsidian.

Origin of obsidian.

Lamination of volcanic rocks.

(MAP 2: THE ISLAND OF ASCENSION.)

This island is situated in the Atlantic Ocean, in latitude 8 degrees S., longitude 14 degrees W. It has the form of an irregular triangle (see Map 2), each side being about six miles in length. Its highest point is 2,870 feet ("Geographical Journal" volume 5 page 243.) above the level of the sea. The whole is volcanic, and, from the absence of proofs to the contrary, I believe of subaerial origin. The fundamental rock is everywhere of a pale colour, generally compact, and of a feldspathic nature. In the S.E. portion of the island, where the highest land is situated, well characterised trachyte, and other congenerous rocks of that varying family, occur. Nearly the entire circumference is covered up by black and rugged streams of basaltic lava, with here and there a hill or single point of rock (one of which near the sea-coast, north of the Fort, is only two or three yards across) of the trachyte still remaining exposed.

BASALTIC ROCKS.

The overlying basaltic lava is in some parts extremely vesicular, in others little so; it is of a black colour, but sometimes contains crystals of glassy feldspar, and seldom much olivine. These streams appear to have possessed singularly little fluidity; their side walls and lower ends being very steep, and even as much as between twenty and thirty feet in height. Their surface is extraordinarily rugged, and from a short distance appears as if studded with small craters. These projections consist of broad, irregularly conical, hillocks, traversed by fissures, and composed of the same unequally scoriaceous basalt with the surrounding streams, but having an obscure tendency to a columnar structure; they rise to a height between ten and thirty feet above the general surface, and have been formed, as I presume, by the heaping up of the viscid lava at points of greater resistance. At the base of several of these hillocks, and occasionally likewise on more level parts, solid ribs, composed of angulo-globular masses of basalt, resembling in size and outline arched sewers or gutters of brickwork, but not being hollow, project between two or three feet above the surface of the streams; what their origin may have been, I do not know. Many of the superficial fragments from these basaltic streams present singularly convoluted forms; and some specimens could hardly be distinguished from logs of dark-coloured wood without their bark.

Many of the basaltic streams can be traced, either to points of eruption at the base of the great central mass of trachyte, or to separate, conical, red-coloured hills, which are scattered over the northern and western borders of the island. Standing on the central eminence, I counted between twenty and thirty of these cones of eruption. The greater number of them had their truncated summits cut off obliquely, and they all sloped towards the S.E., whence the trade-wind blows. (M. Lesson in the "Zoology of the Voyage of the 'Coquille'" page 490 has observed this fact. Mr. Hennah ("Geolog. Proceedings" 1835 page 189) further remarks that the most extensive beds of ashes at Ascension invariably occur on the leeward side of the island.) This structure no doubt has been caused by the ejected fragments and ashes being always blown, during eruptions, in greater quantity towards one side than towards the other. M. Moreau de Jonnes has made a similar observation with respect to the volcanic orifices in the West Indian Islands.

VOLCANIC BOMBS.

(FIGURE 3: FRAGMENT OF A SPHERICAL VOLCANIC BOMB, with the interior parts coarsely cellular, coated by a concentric layer of compact lava, and this again by a crust of finely cellular rock.

FIGURE 4: VOLCANIC BOMB OF OBSIDIAN FROM AUSTRALIA. The upper figure gives a front view; the lower a side view of the same object.)

These occur in great numbers strewed on the ground, and some of them lie at considerable distances from any points of eruption. They vary in size from that of an apple to that of a man's body; they are either spherical or pear-shaped, or with the hinder part (corresponding to the tail of a comet) irregular, studded with projecting points, and even concave. Their surfaces are rough, and fissured with branching cracks; their internal structure is either irregularly scoriaceous and compact, or it presents a symmetrical and very curious appearance. An irregular segment of a bomb of this latter kind, of which I found several, is accurately represented in Figure 3. Its size was about that of a man's head. The whole interior is coarsely cellular; the cells averaging in diameter about the tenth of an inch; but nearer the outside they gradually decrease in size. This part is succeeded by a well-defined shell of compact lava, having a nearly uniform thickness of about the third of an inch; and the shell is overlaid by a somewhat thicker coating of finely cellular lava (the cells varying from the fiftieth to the hundredth of an inch in diameter), which forms the external surface: the line separating the shell of compact lava from the outer scoriaceous crust is distinctly defined. This structure is very simply explained, if we suppose a mass of viscid, scoriaceous matter, to be projected with a rapid, rotatory motion through the air; for whilst the external crust, from cooling, became solidified (in the state we now see it), the centrifugal force, by relieving the pressure in the interior parts of the bomb, would allow the heated vapours to expand their cells; but these being driven by the same force against the already-hardened crust, would become, the nearer they were to this part, smaller and smaller or less expanded, until they became packed into a solid, concentric shell. As we know that chips from a grindstone (Nichol "Architecture of the Heavens.") can be flirted off, when made to revolve with sufficient velocity, we need not doubt that the centrifugal force would have power to modify the structure of a softened bomb, in the manner here supposed. Geologists have remarked, that the external form of a bomb at once bespeaks the history of its aerial course, and few now see that the internal structure can speak, with almost equal plainness, of its rotatory movement.

M. Bory St. Vincent ("Voyage aux Quatre Isles d'Afrique" tome 1 page 222.) has described some balls of lava from the Isle of Bourbon, which have a closely similar structure. His explanation, however (if I understand it rightly), is very different from that which I have given; for he supposes that they have rolled, like snowballs, down the sides of the crater. M. Beudant ("Voyage en Hongrie" tome 2 page 214.), also, has described some singular little balls of obsidian, never more than six or eight inches in diameter, which he found strewed on the surface of the ground: their form is always oval; sometimes they are much swollen in the middle, and even spindle-shaped: their surface is regularly marked with concentric ridges and furrows, all of which on the same ball are at right angles to one axis: their interior is compact and glassy. M. Beudant supposes that masses of lava, when soft, were shot into the air, with a rotatory movement round the same axis, and that the form and superficial ridges of the bombs were thus produced. Sir Thomas Mitchell has given me what at first appears to be the half of a much flattened oval ball of obsidian; it has a singular artificial-like appearance, which is well represented (of the natural size) in Figure 4. It was found in its present state, on a great sandy plain between the rivers Darling and Murray, in Australia, and at the distance of several hundred miles from any known volcanic region. It seems to have been embedded in some reddish tufaceous matter; and may have been transported either by the aborigines or by natural means. The external saucer consists of compact obsidian, of a bottle-green colour, and is filled with finely cellular black lava, much less transparent and glassy than the obsidian. The external surface is marked with four or five not quite perfect ridges, which are represented rather too distinctly in Figure 4. Here, then, we have the external structure described by M. Beudant, and the internal cellular condition of the bombs from Ascension. The lip of the saucer is slightly concave, exactly like the margin of a soup-plate, and its inner edge overlaps a little the central cellular lava. This structure is so symmetrical round the entire circumference, that one is forced to suppose that the bomb burst during its rotatory course, before being quite solidified, and that the lip and edges were thus slightly modified and turned inwards. It may be remarked that the superficial ridges are in planes, at right angles to an axis, transverse to the longer axis of the flattened oval: to explain this circumstance, we may suppose that when the bomb burst, the axis of rotation changed.

AERIFORM EXPLOSIONS.

The flanks of Green Mountain and the surrounding country are covered by a great mass, some hundred feet in thickness, of loose fragments. The lower beds generally consist of fine-grained, slightly consolidated tuffs (Some of this peperino, or tuff, is sufficiently hard not to be broken by the greatest force of the fingers.), and the upper beds of great loose fragments, with alternating finer beds. (On the northern side of the Green Mountain a thin seam, about an inch in thickness, of compact oxide of iron, extends over a considerable area; it lies conformably in the lower part of the stratified mass of ashes and fragments. This substance is of a reddish- brown colour, with an almost metallic lustre; it is not magnetic, but becomes so after having been heated under the blowpipe, by which it is blackened and partly fused. This seam of compact stone, by intercepting the little rain-water which falls on the island, gives rise to a small dripping spring, first discovered by Dampier. It is the only fresh water on the island, so that the possibility of its being inhabited has entirely depended on the occurrence of this ferruginous layer.) One white ribbon- like layer of decomposed, pumiceous breccia, was curiously bent into deep unbroken curves, beneath each of the large fragments in the superincumbent stratum. From the relative position of these beds, I presume that a narrow- mouthed crater, standing nearly in the position of Green Mountain, like a great air-gun, shot forth, before its final extinction, this vast accumulation of loose matter. Subsequently to this event, considerable dislocations have taken place, and an oval circus has been formed by subsidence. This sunken space lies at the north-eastern foot of Green Mountain, and is well represented in Map 2. Its longer axis, which is connected with a N.E. and S.W. line of fissure, is three-fifths of a nautical mile in length; its sides are nearly perpendicular, except in one spot, and about four hundred feet in height; they consist, in the lower part, of a pale basalt with feldspar, and in the upper part, of the tuff and loose ejected fragments; the bottom is smooth and level, and under almost any other climate a deep lake would have been formed here. From the thickness of the bed of loose fragments, with which the surrounding country is covered, the amount of aeriform matter necessary for their projection must have been enormous; hence we may suppose it probable that after the explosions vast subterranean caverns were left, and that the falling in of the roof of one of these produced the hollow here described. At the Galapagos Archipelago, pits of a similar character, but of a much smaller size, frequently occur at the bases of small cones of eruption.

EJECTED GRANITIC FRAGMENTS.

In the neighbourhood of Green Mountain, fragments of extraneous rock are not unfrequently found embedded in the midst of masses of scoriae. Lieutenant Evans, to whose kindness I am indebted for much information, gave me several specimens, and I found others myself. They nearly all have a granitic structure, are brittle, harsh to the touch, and apparently of altered colours.

FIRST, a white syenite, streaked and mottled with red; it consists of well- crystallised feldspar, numerous grains of quartz, and brilliant, though small, crystals of hornblende. The feldspar and hornblende in this and the succeeding cases have been determined by the reflecting goniometer, and the quartz by its action under the blowpipe. The feldspar in these ejected fragments, like the glassy kind in the trachyte, is from its cleavage a potash-feldspar.

SECONDLY, a brick-red mass of feldspar, quartz, and small dark patches of a decayed mineral; one minute particle of which I was able to ascertain, by its cleavage, to be hornblende.

THIRDLY, a mass of confusedly crystallised white feldspar, with little nests of a dark-coloured mineral, often carious, externally rounded, having a glossy fracture, but no distinct cleavage: from comparison with the second specimen, I have no doubt that it is fused hornblende.

FOURTHLY, a rock, which at first appears a simple aggregation of distinct and large-sized crystals of dusty-coloured Labrador feldspar (Professor Miller has been so kind as to examine this mineral. He obtained two good cleavages of 86 degrees 30 minutes and 86 degrees 50 minutes. The mean of several, which I made, was 86 degrees 30 minutes. Professor Miller states that these crystals, when reduced to a fine powder, are soluble in hydrochloric acid, leaving some undissolved silex behind; the addition of oxalate of ammonia gives a copious precipitate of lime. He further remarks, that according to Von Kobell, anorthite (a mineral occurring in the ejected fragments at Mount Somma) is always white and transparent, so that if this be the case, these crystals from Ascension must be considered as Labrador feldspar. Professor Miller adds, that he has seen an account, in Erdmann's "Journal fur tecnische Chemie," of a mineral ejected from a volcano which had the external characters of Labrador feldspar, but differed in the analysis from that given by mineralogists of this mineral: the author attributed this difference to an error in the analysis of Labrador feldspar, which is very old.); but in their interstices there is some white granular feldspar, abundant scales of mica, a little altered hornblende, and, as I believe, no quartz. I have described these fragments in detail, because it is rare to find granitic rocks ejected from volcanoes with their MINERALS UNCHANGED, as is the case with the first specimen, and partially with the second. (Daubeny, in his work on Volcanoes page 386, remarks that this is the case; and Humboldt, in his "Personal Narrative" volume 1 page 236, says "In general, the masses of known primitive rocks, I mean those which perfectly resemble our granites, gneiss, and mica-slate, are very rare in lavas: the substances we generally denote by the name of granite, thrown out by Vesuvius, are mixtures of nepheline, mica, and pyroxene.") One other large fragment, found in another spot, is deserving of notice; it is a conglomerate, containing small fragments of granitic, cellular, and jaspery rocks, and of hornstone porphyries, embedded in a base of wacke, threaded by numerous thin layers of a concretionary pitchstone passing into obsidian. These layers are parallel, slightly tortuous, and short; they thin out at their ends, and resemble in form the layers of quartz in gneiss. It is probable that these small embedded fragments were not separately ejected, but were entangled in a fluid volcanic rock, allied to obsidian; and we shall presently see that several varieties of this latter series of rock assume a laminated structure.

TRACHYTIC SERIES OF ROCKS.

Those occupy the more elevated and central, and likewise the south-eastern, parts of the island. The trachyte is generally of a pale brown colour, stained with small darker patches; it contains broken and bent crystals of glassy feldspar, grains of specular iron, and black microscopical points, which latter, from being easily fused, and then becoming magnetic, I presume are hornblende. The greater number of the hills, however, are composed of a quite white, friable stone, appearing like a trachytic tuff. Obsidian, hornstone, and several kinds of laminated feldspathic rocks, are associated with the trachyte. There is no distinct stratification; nor could I distinguish a crateriform structure in any of the hills of this series. Considerable dislocations have taken place; and many fissures in these rocks are yet left open, or are only partially filled with loose fragments. Within the space (This space is nearly included by a line sweeping round Green Mountain, and joining the hills, called the Weather Port Signal, Holyhead, and that denominated (improperly in a geological sense) "the Crater of an old volcano."), mainly formed of trachyte, some basaltic streams have burst forth; and not far from the summit of Green Mountain, there is one stream of quite black, vesicular basalt, containing minute crystals of glassy feldspar, which have a rounded appearance.

The soft white stone above mentioned is remarkable from its singular resemblance, when viewed in mass, to a sedimentary tuff: it was long before I could persuade myself that such was not its origin; and other geologists have been perplexed by closely similar formations in trachytic regions. In two cases, this white earthy stone formed isolated hills; in a third, it was associated with columnar and laminated trachyte; but I was unable to trace an actual junction. It contains numerous crystals of glassy feldspar and black microscopical specks, and is marked with small darker patches, exactly as in the surrounding trachyte. Its basis, however, when viewed under the microscope, is generally quite earthy; but sometimes it exhibits a decidedly crystalline structure. On the hill marked "Crater of an old volcano," it passes into a pale greenish-grey variety, differing only in its colour, and in not being so earthy; the passage was in one case effected insensibly; in another, it was formed by numerous, rounded and angular, masses of the greenish variety, being embedded in the white variety;-in this latter case, the appearance was very much like that of a sedimentary deposit, torn up and abraded during the deposition of a subsequent stratum. Both these varieties are traversed by innumerable tortuous veins (presently to be described), which are totally unlike injected dikes, or indeed any other veins which I have ever seen. Both varieties include a few scattered fragments, large and small, of dark- coloured scoriaceous rocks, the cells of some of which are partially filled with the white earthy stone; they likewise include some huge blocks of a cellular porphyry. (The porphyry is dark coloured; it contains numerous, often fractured, crystals of white opaque feldspar, also decomposing crystals of oxide of iron; its vesicles include masses of delicate, hair- like, crystals, apparently of analcime.) These fragments project from the weathered surface, and perfectly resemble fragments embedded in a true sedimentary tuff. But as it is known that extraneous fragments of cellular rock are sometimes included in columnar trachyte, in phonolite (D'Aubuisson "Traite de Geognosie" tome 2 page 548.), and in other compact lavas, this circumstance is not any real argument for the sedimentary origin of the white earthy stone. (Dr. Daubeny on Volcanoes, page 180 seems to have been led to believe that certain trachytic formations of Ischia and of the Puy de Dome, which closely resemble these of Ascension, were of sedimentary origin, chiefly from the frequent presence in them "of scoriform portions, different in colour from the matrix." Dr. Daubeny adds, that on the other hand, Brocchi, and other eminent geologists, have considered these beds as earthy varieties of trachyte; he considers the subject deserving of further attention.) The insensible passage of the greenish variety into the white one, and likewise the more abrupt passage by fragments of the former being embedded in the latter, might result from slight differences in the composition of the same mass of molten stone, and from the abrading action of one such part still fluid on another part already solidified. The curiously formed veins have, I believe, been formed by siliceous matter being subsequently segregated. But my chief reason for believing that these soft earthy stones, with their extraneous fragments, are not of sedimentary origin, is the extreme improbability of crystals of feldspar, black microscopical specks, and small stains of a darker colour occurring in the same proportional numbers in an aqueous deposit, and in masses of solid trachyte. Moreover, as I have remarked, the microscope occasionally reveals a crystalline structure in the apparently earthy basis. On the other hand, the partial decomposition of such great masses of trachyte, forming whole mountains, is undoubtedly a circumstance of not easy explanation.

VEINS IN THE EARTHY TRACHYTIC MASSES.

These veins are extraordinarily numerous, intersecting in the most complicated manner both coloured varieties of the earthy trachyte: they are best seen on the flanks of the "Crater of the old volcano." They contain crystals of glassy feldspar, black microscopical specks and little dark stains, precisely as in the surrounding rock; but the basis is very different, being exceedingly hard, compact, somewhat brittle, and of rather less easy fusibility. The veins vary much, and suddenly, from the tenth of an inch to one inch in thickness; they often thin out, not only on their edges, but in their central parts, thus leaving round, irregular apertures; their surfaces are rugged. They are inclined at every possible angle with the horizon, or are horizontal; they are generally curvilinear, and often interbranch one with another. From their hardness they withstand weathering, and projecting two or three feet above the ground, they occasionally extend some yards in length; these plate-like veins, when struck, emit a sound, almost like that of a drum, and they may be distinctly seen to vibrate; their fragments, which are strewed on the ground, clatter like pieces of iron when knocked against each other. They often assume the most singular forms; I saw a pedestal of the earthy trachyte, covered by a hemispherical portion of a vein, like a great umbrella, sufficiently large to shelter two persons. I have never met with, or seen described, any veins like these; but in form they resemble the ferruginous seams, due to some process of segregation, occurring not uncommonly in sandstones,-for instance, in the New Red sandstone of England. Numerous veins of jasper and of siliceous sinter, occurring on the summit of this same hill, show that there has been some abundant source of silica, and as these plate-like veins differ from the trachyte only in their greater hardness, brittleness, and less easy fusibility, it appears probable that their origin is due to the segregation or infiltration of siliceous matter, in the same manner as happens with the oxides of iron in many sedimentary rocks.

SILICEOUS SINTER AND JASPER.

The siliceous sinter is either quite white, of little specific gravity, and with a somewhat pearly fracture, passing into pinkish pearl quartz; or it is yellowish white, with a harsh fracture, and it then contains an earthy powder in small cavities. Both varieties occur, either in large irregular masses in the altered trachyte, or in seams included in broad, vertical, tortuous, irregular veins of a compact, harsh stone of a dull red colour, appearing like a sandstone. This stone, however, is only altered trachyte; and a nearly similar variety, but often honeycombed, sometimes adheres to the projecting plate-like veins, described in the last paragraph. The jasper is of an ochre yellow or red colour; it occurs in large irregular masses, and sometimes in veins, both in the altered trachyte and in an associated mass of scoriaceous basalt. The cells of the scoriaceous basalt are lined or filled with fine, concentric layers of chalcedony, coated and studded with bright-red oxide of iron. In this rock, especially in the rather more compact parts, irregular angular patches of the red jasper are included, the edges of which insensibly blend into the surrounding mass; other patches occur having an intermediate character between perfect jasper and the ferruginous, decomposed, basaltic base. In these patches, and likewise in the large vein-like masses of jasper, there occur little rounded cavities, of exactly the same size and form with the air-cells, which in the scoriaceous basalt are filled and lined with layers of chalcedony. Small fragments of the jasper, examined under the microscope, seem to resemble the chalcedony with its colouring matter not separated into layers, but mingled in the siliceous paste, together with some impurities. I can understand these facts,-namely, the blending of the jasper into the semi-decomposed basalt,-its occurrence in angular patches, which clearly do not occupy pre-existing hollows in the rock,-and its containing little vesicles filled with chalcedony, like those in the scoriaceous lava,-only on the supposition that a fluid, probably the same fluid which deposited the chalcedony in the air-cells, removed in those parts where there were no cavities, the ingredients of the basaltic rock, and left in their place silica and iron, and thus produced the jasper. In some specimens of silicified wood, I have observed, that in the same manner as in the basalt, the solid parts were converted into a dark-coloured homogeneous stone, whereas the cavities formed by the larger sap-vessels (which may be compared with the air-vesicles in the basaltic lava) and other irregular hollows, apparently produced by decay, were filled with concentric layers of chalcedony; in this case, there can be little doubt that the same fluid deposited the homogeneous base and the chalcedonic layers. After these considerations, I cannot doubt but that the jasper of Ascension may be viewed as a volcanic rock silicified, in precisely the same sense as this term is applied to wood, when silicified; we are equally ignorant of the means by which every atom of wood, whilst in a perfect state, is removed and replaced by atoms of silica, as we are of the means by which the constituent parts of a volcanic rock could be thus acted on. (Beudant "Voyage en Hongrie" tome 3 pages 502, 504 describes kidney-shaped masses of jasper-opal, which either blend into the surrounding trachytic conglomerate, or are embedded in it like chalk-flints; and he compares them with the fragments of opalised wood, which are abundant in this same formation. Beudant, however, appears to have viewed the process of their formation rather as one of simple infiltration than of molecular exchange; but the presence of a concretion, wholly different from the surrounding matter, if not formed in a pre-existing hollow, clearly seems to me to require, either a molecular or mechanical displacement of the atoms, which occupied the space afterwards filled by it. The jasper-opal of Hungary passes into chalcedony, and therefore in this case, as in that of Ascension, jasper seems to be intimately related in origin with chalcedony.) I was led to the careful examination of these rocks, and to the conclusion here given, from having heard the Rev. Professor Henslow express a similar opinion, regarding the origin in trap-rocks of many chalcedonies and agates. Siliceous deposits seem to be very general, if not of universal occurrence, in partially decomposed trachytic tuffs (Beudant "Voyage Min." tome 3 page 507 enumerates cases in Hungary, Germany, Central France, Italy, Greece, and Mexico.); and as these hills, according to the view above given, consist of trachyte softened and altered in situ, the presence of free silica in this case may be added as one more instance to the list.

CONCRETIONS IN PUMICEOUS TUFF.

The hill, marked in Map 2 "Crater of an old volcano," has no claims to this appellation, which I could discover, except in being surmounted by a circular, very shallow, saucer-like summit, nearly half a mile in diameter. This hollow has been nearly filled up with many successive sheets of ashes and scoriae, of different colours, and slightly consolidated. Each successive saucer-shaped layer crops out all round the margin, forming so many rings of various colours, and giving to the hill a fantastic appearance. The outer ring is broad, and of a white colour; hence it resembles a course round which horses have been exercised, and has received the name of the Devil's Riding School, by which it is most generally known. These successive layers of ashes must have fallen over the whole surrounding country, but they have all been blown away except in this one hollow, in which probably moisture accumulated, either during an extraordinary year when rain fell, or during the storms often accompanying volcanic eruptions. One of the layers of a pinkish colour, and chiefly derived from small, decomposed fragments of pumice, is remarkable, from containing numerous concretions. These are generally spherical, from half an inch to three inches in diameter; but they are occasionally cylindrical, like those of iron-pyrites in the chalk of Europe. They consist of a very tough, compact, pale-brown stone, with a smooth and even fracture. They are divided into concentric layers by thin white partitions, resembling the external superficies; six or eight of such layers are distinctly defined near the outside; but those towards the inside generally become indistinct, and blend into a homogeneous mass. I presume that these concentric layers were formed by the shrinking of the concretion, as it became compact. The interior part is generally fissured by minute cracks or septaria, which are lined, both by black, metallic, and by other white and crystalline specks, the nature of which I was unable to ascertain. Some of the larger concretions consist of a mere spherical shell, filled with slightly consolidated ashes. The concretions contain a small proportion of carbonate of lime: a fragment placed under the blowpipe decrepitates, then whitens and fuses into a blebby enamel, but does not become caustic. The surrounding ashes do not contain any carbonate of lime; hence the concretions have probably been formed, as is so often the case, by the aggregation of this substance. I have not met with any account of similar concretions; and considering their great toughness and compactness, their occurrence in a bed, which probably has been subjected only to atmospheric moisture, is remarkable.

FORMATION OF CALCAREOUS ROCKS ON THE SEA-COAST.

On several of the sea-beaches, there are immense accumulations of small, well-rounded particles of shells and corals, of white, yellowish, and pink colours, interspersed with a few volcanic particles. At the depth of a few feet, these are found cemented together into stone, of which the softer varieties are used for building; there are other varieties, both coarse and fine-grained, too hard for this purpose: and I saw one mass divided into even layers half an inch in thickness, which were so compact that when struck with a hammer they rang like flint. It is believed by the inhabitants, that the particles become united in the course of a single year. The union is effected by calcareous matter; and in the most compact varieties, each rounded particle of shell and volcanic rock can be distinctly seen to be enveloped in a husk of pellucid carbonate of lime. Extremely few perfect shells are embedded in these agglutinated masses; and I have examined even a large fragment under a microscope, without being able to discover the least vestige of striae or other marks of external form: this shows how long each particle must have been rolled about, before its turn came to be embedded and cemented. (The eggs of the turtle being buried by the parent, sometimes become enclosed in the solid rock. Mr. Lyell has given a figure ("Principles of Geology" book 3 chapter 17) of some eggs, containing the bones of young turtles, found thus entombed.) One of the most compact varieties, when placed in acid, was entirely dissolved, with the exception of some flocculent animal matter; its specific gravity was 2.63. The specific gravity of ordinary limestone varies from 2.6 to 2.75; pure Carrara marble was found by Sir H. De la Beche to be 2.7. ("Researches in Theoretical Geology" page 12.) It is remarkable that these rocks of Ascension, formed close to the surface, should be nearly as compact as marble, which has undergone the action of heat and pressure in the plutonic regions.

The great accumulation of loose calcareous particles, lying on the beach near the Settlement, commences in the month of October, moving towards the S.W., which, as I was informed by Lieutenant Evans, is caused by a change in the prevailing direction of the currents. At this period the tidal rocks, at the S.W. end of the beach, where the calcareous sand is accumulating, and round which the currents sweep, become gradually coated with a calcareous incrustation, half an inch in thickness. It is quite white, compact, with some parts slightly spathose, and is firmly attached to the rock. After a short time it gradually disappears, being either redissolved, when the water is less charged with lime, or more probably is mechanically abraded. Lieutenant Evans has observed these facts, during the six years he has resided at Ascension. The incrustation varies in thickness in different years: in 1831 it was unusually thick. When I was there in July, there was no remnant of the incrustation; but on a point of basalt, from which the quarrymen had lately removed a mass of the calcareous freestone, the incrustation was perfectly preserved. Considering the position of the tidal-rocks, and the period at which they become coated, there can be no doubt that the movement and disturbance of the vast accumulation of calcareous particles, many of them being partially agglutinated together, cause the waves of the sea to be so highly charged with carbonate of lime, that they deposit it on the first objects against which they impinge. I have been informed by Lieutenant Holland, R.N., that this incrustation is formed on many parts of the coast, on most of which, I believe, there are likewise great masses of comminuted shells.

A FRONDESCENT CALCAREOUS INCRUSTATION.

(FIGURE 5. AN INCRUSTATION OF CALCAREOUS AND ANIMAL MATTER, coating the tidal-rocks at Ascension.)

In many respects this is a singular deposit; it coats throughout the year the tidal volcanic rocks, that project from the beaches composed of broken shells. Its general appearance is well represented in Figure 5; but the fronds or discs, of which it is composed, are generally so closely crowded together as to touch. These fronds have their sinuous edges finely crenulated, and they project over their pedestals or supports; their upper surfaces are either slightly concave, or slightly convex; they are highly polished, and of a dark grey or jet black colour; their form is irregular, generally circular, and from the tenth of an inch to one inch and a half in diameter; their thickness, or amount of their projection from the rock on which they stand, varies much, about a quarter of an inch being perhaps most usual. The fronds occasionally become more and more convex, until they pass into botryoidal masses with their summits fissured; when in this state, they are glossy and of an intense black, so as to resemble some fused metallic substance. I have shown the incrustation, both in this latter and in its ordinary state to several geologists, but not one could conjecture its origin, except that perhaps it was of volcanic nature!

The substance forming the fronds has a very compact and often almost crystalline fracture; the edges being translucent, and hard enough easily to scratch calcareous spar. Under the blowpipe it immediately becomes white, and emits a strong animal odour, like that from fresh shells. It is chiefly composed of carbonate of lime; when placed in muriatic acid it froths much, leaving a residue of sulphate of lime, and of an oxide of iron, together with a black powder, which is not soluble in heated acids. This latter substance seems to be carbonaceous, and is evidently the colouring matter. The sulphate of lime is extraneous, and occurs in distinct, excessively minute, lamellar plates, studded on the surface of the fronds, and embedded between the fine layers of which they are composed; when a fragment is heated in the blowpipe, these lamellae are immediately rendered visible. The original outline of the fronds may often be traced, either to a minute particle of shell fixed in a crevice of the rock, or to several cemented together; these first become deeply corroded, by the dissolving power of the waves, into sharp ridges, and then are coated with successive layers of the glossy, grey, calcareous incrustation. The inequalities of the primary support affect the outline of every successive layer, in the same manner as may often be seen in bezoar-stones, when an object like a nail forms the centre of aggregation. The crenulated edges, however, of the frond appear to be due to the corroding power of the surf on its own deposit, alternating with fresh depositions. On some smooth basaltic rocks on the coast of St. Jago, I found an exceedingly thin layer of brown calcareous matter, which under a lens presented a miniature likeness of the crenulated and polished fronds of Ascension; in this case a basis was not afforded by any projecting extraneous particles. Although the incrustation at Ascension is persistent throughout the year; yet from the abraded appearance of some parts, and from the fresh appearance of other parts, the whole seems to undergo a round of decay and renovation, due probably to changes in the form of the shifting beach, and consequently in the action of the breakers: hence probably it is, that the incrustation never acquires a great thickness. Considering the position of the encrusted rocks in the midst of the calcareous beach, together with its composition, I think there can be no doubt that its origin is due to the dissolution and subsequent deposition of the matter composing the rounded particles of shells and corals. (The selenite, as I have remarked is extraneous, and must have been derived from the sea-water. It is an interesting circumstance thus to find the waves of the ocean, sufficiently charged with sulphate of lime, to deposit it on the rocks, against which they dash every tide. Dr. Webster has described ("Voyage of the 'Chanticleer'" volume 2 page 319) beds of gypsum and salt, as much as two feet in thickness, left by the evaporation of the spray on the rocks on the windward coast. Beautiful stalactites of selenite, resembling in form those of carbonate of lime, are formed near these beds. Amorphous masses of gypsum, also, occur in caverns in the interior of the island; and at Cross Hill (an old crater) I saw a considerable quantity of salt oozing from a pile of scoriae. In these latter cases, the salt and gypsum appear to be volcanic products.) From this source it derives its animal matter, which is evidently the colouring principle. The nature of the deposit, in its incipient stage, can often be well seen upon a fragment of white shell, when jammed between two of the fronds; it then appears exactly like the thinnest wash of a pale grey varnish. Its darkness varies a little, but the jet blackness of some of the fronds and of the botryoidal masses seems due to the translucency of the successive grey layers. There is, however, this singular circumstance, that when deposited on the under side of ledges of rock or in fissures, it appears always to be of a pale, pearly grey colour, even when of considerable thickness: hence one is led to suppose, that an abundance of light is necessary to the development of the dark colour, in the same manner as seems to be the case with the upper and exposed surfaces of the shells of living mollusca, which are always dark, compared with their under surfaces and with the parts habitually covered by the mantle of the animal. In this circumstance,-in the immediate loss of colour and in the odour emitted under the blowpipe,-in the degree of hardness and translucency of the edges,-and in the beautiful polish of the surface (From the fact described in my "Journal of Researches" of a coating of oxide of iron, deposited by a streamlet on the rocks in its bed (like a nearly similar coating at the great cataracts of the Orinoco and Nile), becoming finely polished where the surf acts, I presume that the surf in this instance, also, is the polishing agent.), rivalling when in a fresh state that of the finest Oliva, there is a striking analogy between this inorganic incrustation and the shells of living molluscous animals. (In the section descriptive of St. Paul's Rocks, I have described a glossy, pearly substance, which coats the rocks, and an allied stalactitical incrustation from Ascension, the crust of which resembles the enamel of teeth, but is hard enough to scratch plate-glass. Both these substances contain animal matter, and seem to have been derived from water in filtering through birds' dung.) This appears to me to be an interesting physiological fact. (Mr. Horner and Sir David Brewster have described "Philosophical Transactions" 1836 page 65 a singular "artificial substance, resembling shell." It is deposited in fine, transparent, highly polished, brown- coloured laminae, possessing peculiar optical properties, on the inside of a vessel, in which cloth, first prepared with glue and then with lime, is made to revolve rapidly in water. It is much softer, more transparent, and contains more animal matter, than the natural incrustation at Ascension; but we here again see the strong tendency which carbonate of lime and animal matter evince to form a solid substance allied to shell.)

SINGULAR LAMINATED BEDS ALTERNATING WITH AND PASSING INTO OBSIDIAN.

These beds occur within the trachytic district, at the western base of Green Mountain, under which they dip at a high inclination. They are only partially exposed, being covered up by modern ejections; from this cause, I was unable to trace their junction with the trachyte, or to discover whether they had flowed as a stream of lava, or had been injected amidst the overlying strata. There are three principal beds of obsidian, of which the thickest forms the base of the section. The alternating stony layers appear to me eminently curious, and shall be first described, and afterwards their passage into the obsidian. They have an extremely diversified appearance; five principal varieties may be noticed, but these insensibly blend into each other by endless gradations.

FIRST.

A pale grey, irregularly and coarsely laminated (This term is open to some misinterpretation, as it may be applied both to rocks divided into laminae of exactly the same composition, and to layers firmly attached to each other, with no fissile tendency, but composed of different minerals, or of different shades of colour. The term "laminated," in this chapter, is applied in these latter senses; where a homogeneous rock splits, as in the former sense, in a given direction, like clay-slate, I have used the term "fissile."), harsh-feeling rock, resembling clay-slate which has been in contact with a trap-dike, and with a fracture of about the same degree of crystalline structure. This rock, as well as the following varieties, easily fuses into a pale glass. The greater part is honeycombed with irregular, angular, cavities, so that the whole has a curious appearance, and some fragments resemble in a remarkable manner silicified logs of decayed wood. This variety, especially where more compact, is often marked with thin whitish streaks, which are either straight or wrap round, one behind the other, the elongated carious hollows.

SECONDLY.

A bluish grey or pale brown, compact, heavy, homogeneous stone, with an angular, uneven, earthy fracture; viewed, however, under a lens of high power, the fracture is seen to be distinctly crystalline, and even separate minerals can be distinguished.

THIRDLY.

A stone of the same kind with the last, but streaked with numerous, parallel, slightly tortuous, white lines of the thickness of hairs. These white lines are more crystalline than the parts between them; and the stone splits along them: they frequently expand into exceedingly thin cavities, which are often only just perceptible with a lens. The matter forming the white lines becomes better crystallised in these cavities, and Professor Miller was fortunate enough, after several trials, to ascertain that the white crystals, which are the largest, were of quartz (Professor Miller informs me that the crystals which he measured had the faces P, z, m of the figure (147) given by Haidinger in his Translation of Mohs; and he adds, that it is remarkable, that none of them had the slightest trace of faces r of the regular six-sided prism.), and that the minute green transparent needles were augite, or, as they would more generally be called, diopside: besides these crystals, there are some minute, dark specks without a trace of crystalline, and some fine, white, granular, crystalline matter which is probably feldspar. Minute fragments of this rock are easily fusible.

FOURTHLY.

A compact crystalline rock, banded in straight lines with innumerable layers of white and grey shades of colour, varying in width from the thirtieth to the two-hundredth of an inch; these layers seem to be composed chiefly of feldspar, and they contain numerous perfect crystals of glassy feldspar, which are placed lengthways; they are also thickly studded with microscopically minute, amorphous, black specks, which are placed in rows, either standing separately, or more frequently united, two or three or several together, into black lines, thinner than a hair. When a small fragment is heated in the blowpipe, the black specks are easily fused into black brilliant beads, which become magnetic,-characters that apply to no common mineral except hornblende or augite. With the black specks there are mingled some others of a red colour, which are magnetic before being heated, and no doubt are oxide of iron. Round two little cavities, in a specimen of this variety, I found the black specks aggregated into minute crystals, appearing like those of augite or hornblende, but too dull and small to be measured by the goniometer; in the specimen, also, I could distinguish amidst the crystalline feldspar, grains, which had the aspect of quartz. By trying with a parallel ruler, I found that the thin grey layers and the black hair-like lines were absolutely straight and parallel to each other. It is impossible to trace the gradation from the homogeneous grey rocks to these striped varieties, or indeed the character of the different layers in the same specimen, without feeling convinced that the more or less perfect whiteness of the crystalline feldspathic matter depends on the more or less perfect aggregation of diffused matter, into the black and red specks of hornblende and oxide of iron.

FIFTHLY.

A compact heavy rock, not laminated, with an irregular, angular, highly crystalline, fracture; it abounds with distinct crystals of glassy feldspar, and the crystalline feldspathic base is mottled with a black mineral, which on the weathered surface is seen to be aggregated into small crystals, some perfect, but the greater number imperfect. I showed this specimen to an experienced geologist, and asked him what it was; he answered, as I think every one else would have done, that it was a primitive greenstone. The weathered surface, also, of the banded variety in Figure 4, strikingly resembles a worn fragment of finely laminated gneiss.

These five varieties, with many intermediate ones, pass and repass into each other. As the compact varieties are quite subordinate to the others, the whole may be considered as laminated or striped. The laminae, to sum up their characteristics, are either quite straight, or slightly tortuous, or convoluted; they are all parallel to each other, and to the intercalating strata of obsidian; they are generally of extreme thinness; they consist either of an apparently homogeneous, compact rock, striped with different shades of grey and brown colours, or of crystalline feldspathic layers in a more or less perfect state of purity, and of different thicknesses, with distinct crystals of glassy feldspar placed lengthways, or of very thin layers chiefly composed of minute crystals of quartz and augite, or composed of black and red specks of an augitic mineral and of an oxide of iron, either not crystallised or imperfectly so. After having fully described the obsidian, I shall return to the subject of the lamination of rocks of the trachytic series.

The passage of the foregoing beds into the strata of glassy obsidian is effected in several ways: first, angulo-modular masses of obsidian, both large and small, abruptly appear disseminated in a slaty, or in an amorphous, pale-coloured, feldspathic rock, with a somewhat pearly fracture. Secondly, small irregular nodules of the obsidian, either standing separately, or united into thin layers, seldom more than the tenth of an inch in thickness, alternate repeatedly with very thin layers of a feldspathic rock, which is striped with the finest parallel zones of colour, like an agate, and which sometimes passes into the nature of pitchstone; the interstices between the nodules of obsidian are generally filled by soft white matter, resembling pumiceous ashes. Thirdly, the whole substance of the bounding rock suddenly passes into an angulo-concretionary mass of obsidian. Such masses (as well as the small nodules) of obsidian are of a pale green colour, and are generally streaked with different shades of colour, parallel to the laminae of the surrounding rock; they likewise generally contain minute white sphaerulites, of which half is sometimes embedded in a zone of one shade of colour, and half in a zone of another shade. The obsidian assumes its jet black colour and perfectly conchoidal fracture, only when in large masses; but even in these, on careful examination and on holding the specimens in different lights, I could generally distinguish parallel streaks of different shades of darkness.

(FIGURE 6. OPAQUE BROWN SPHAERULITES, drawn on an enlarged scale. The upper ones are externally marked with parallel ridges. The internal radiating structure of the lower ones, is much too plainly represented.

FIGURE 7. A LAYER FORMED BY THE UNION OF MINUTE BROWN SPHAERULITES, INTERSECTING TWO OTHER SIMILAR LAYERS: the whole represented of nearly the natural size.)

One of the commonest transitional rocks deserves in several respects a further description. It is of a very complicated nature, and consists of numerous thin, slightly tortuous layers of a pale-coloured feldspathic stone, often passing into an imperfect pitchstone, alternating with layers formed of numberless little globules of two varieties of obsidian, and of two kinds of sphaerulites, embedded in a soft or in a hard pearly base. The sphaerulites are either white and translucent, or dark brown and opaque; the former are quite spherical, of small size, and distinctly radiated from their centre. The dark brown sphaerulites are less perfectly round, and vary in diameter from the twentieth to the thirtieth of an inch; when broken they exhibit towards their centres, which are whitish, an obscure radiating structure; two of them when united sometimes have only one central point of radiation; there is occasionally a trace of or a hollow crevice in their centres. They stand either separately, or are united two or three or many together into irregular groups, or more commonly into layers, parallel to the stratification of the mass. This union in many cases is so perfect, that the two sides of the layer thus formed, are quite even; and these layers, as they become less brown and opaque, cannot be distinguished from the alternating layers of the pale-coloured feldspathic stone. The sphaerulites, when not united, are generally compressed in the plane of the lamination of the mass; and in this same plane, they are often marked internally, by zones of different shades of colour, and externally by small ridges and furrows. In the upper part of Figure 6, the sphaerulites with the parallel ridges and furrows are represented on an enlarged scale, but they are not well executed; and in the lower part, their usual manner of grouping is shown. In another specimen, a thin layer formed of the brown sphaerulites closely united together, intersects, as represented in Figure 7, a layer of similar composition; and after running for a short space in a slightly curved line, again intersects it, and likewise a second layer lying a little way beneath that first intersected. The small nodules also of obsidian are sometimes externally marked with ridges and furrows, parallel to the lamination of the mass, but always less plainly than the sphaerulites. These obsidian nodules are generally angular, with their edges blunted: they are often impressed with the form of the adjoining sphaerulites, than which they are always larger; the separate nodules seldom appear to have drawn each other out by exerting a mutually attractive force. Had I not found in some cases, a distinct centre of attraction in these nodules of obsidian, I should have been led to have considered them as residuary matter, left during the formation of the pearlstone, in which they are embedded, and of the sphaerulitic globules.

The sphaerulites and the little nodules of obsidian in these rocks so closely resemble, in general form and structure, concretions in sedimentary deposits, that one is at once tempted to attribute to them an analogous origin. They resemble ordinary concretions in the following respects: in their external form,-in the union of two or three, or of several, into an irregular mass, or into an even-sided layer,-in the occasional intersection of one such layer by another, as in the case of chalk-flints,- -in the presence of two or three kinds of nodules, often close together, in the same basis,-in their fibrous, radiating structure, with occasional hollows in their centres,-in the co-existence of a laminary, concretionary, and radiating structure, as is so well developed in the concretions of magnesian limestone, described by Professor Sedgwick. ("Geological Transactions" volume 3 part 1 page 37.) Concretions in sedimentary deposits, it is known, are due to the separation from the surrounding mass of the whole or part of some mineral substance, and its aggregation round certain points of attraction. Guided by this fact, I have endeavoured to discover whether obsidian and the sphaerulites (to which may be added marekanite and pearlstone, both of them occurring in nodular concretions in the trachytic series) differ in their constituent parts, from the minerals generally composing trachytic rocks. It appears from three analyses, that obsidian contains on an average 76 per cent of silica; from one analysis, that sphaerulites contain 79.12; from two, that marekanite contains 79.25; and from two other analyses, that pearlstone contains 75.62 of silica. (The foregoing analyses are taken from Beudant "Traite de Mineralogie" tome 2 page 113; and one analysis of obsidian from Phillips "Mineralogy.") Now, the constituent parts of trachyte, as far as they can be distinguished consist of feldspar, containing 65.21 of silica; or of albite, containing 69.09; of hornblende, containing 55.27 (These analyses are taken from Von Kobell "Grundzuge der Mineralogie" 1838.), and of oxide of iron: so that the foregoing glassy concretionary substances all contain a larger proportion of silica than that occurring in ordinary feldspathic or trachytic rocks. D'Aubuisson ("Traite de Geogn." tome 2 page 535.), also, has remarked on the large proportion of silica compared with alumina, in six analyses of obsidian and pearlstone given in Brongniart's "Mineralogy." Hence I conclude, that the foregoing concretions have been formed by a process of aggregation, strictly analogous to that which takes place in aqueous deposits, acting chiefly on the silica, but likewise on some of the other elements of the surrounding mass, and thus producing the different concretionary varieties. From the well-known effects of rapid cooling (This is seen in the manufacture of common glass, and in Gregory Watts's experiments on molten trap; also on the natural surfaces of lava- streams, and on the side-walls of dikes.) in giving glassiness of texture, it is probably necessary that the entire mass, in cases like that of Ascension, should have cooled at a certain rate; but considering the repeated and complicated alterations of nodules and thin layers of a glassy texture with other layers quite stony or crystalline, all within the space of a few feet or even inches, it is hardly possible that they could have cooled at different rates, and thus have acquired their different textures.

The natural sphaerulites in these rocks very closely resemble those produced in glass, when slowly cooled. (I do not know whether it is generally known, that bodies having exactly the same appearance as sphaerulites, sometimes occur in agates. Mr. Robert Brown showed me in an agate, formed within a cavity in a piece of silicified wood, some little specks, which were only just visible to the naked eye: these specks, when placed by him under a lens of high power, presented a beautiful appearance: they were perfectly circular, and consisted of the finest fibres of a brown colour, radiating with great exactness from a common centre. These little radiating stars are occasionally intersected, and portions are quite cut off by the fine, ribbon-like zones of colour in the agate. In the obsidian of Ascension, the halves of a sphaerulite often lie in different zones of colour, but they are not cut off by them, as in the agate.) In some fine specimens of partially devitrified glass, in the possession of Mr. Stokes, the sphaerulites are united into straight layers with even sides, parallel to each other, and to one of the outer surfaces, exactly as in the obsidian. These layers sometimes interbranch and form loops; but I did not see any case of actual intersection. They form the passage from the perfectly glassy portions, to those nearly homogeneous and stony, with only an obscure concretionary structure. In the same specimen, also, sphaerulites differing slightly in colour and in structure, occur embedded close together. Considering these facts, it is some confirmation of the view above given of the concretionary origin of the obsidian and natural sphaerulites, to find that M. Dartigues ("Journal de Physique" tome 59 1804 pages 10, 12.), in his curious paper on this subject, attributes the production of sphaerulites in glass, to the different ingredients obeying their own laws of attraction and becoming aggregated. He is led to believe that this takes place, from the difficulty in remelting sphaerulitic glass, without the whole be first thoroughly pounded and mixed together; and likewise from the fact, that the change takes place most readily in glass composed of many ingredients. In confirmation of M. Dartigues' view, I may remark, that M. Fleuriau de Bellevue (Idem tome 60 1805 page 418.) found that the sphaerulitic portions of devitrified glass were acted on both by nitric acid and under the blowpipe, in a different manner from the compact paste in which they were embedded.

COMPARISON OF THE OBSIDIAN BEDS AND ALTERNATING STRATA OF ASCENSION, WITH THOSE OF OTHER COUNTRIES.

I have been struck with much surprise, how closely the excellent description of the obsidian rocks of Hungary, given by Beudant ("Voyage en Hongrie" tome 1 page 330; tome 2 pages 221 and 315; tome 3 pages 369, 371, 377, 381.), and that by Humboldt, of the same formation in Mexico and Peru ("Essai Geognostique" pages 176, 326, 328.), and likewise the descriptions given by several authors (P. Scrope "Geological Transactions" volume 2 second series page 195. Consult also Dolomieu "Voyage aux Isles Lipari" and D'Aubuisson "Traite de Geogn." tome 2 page 534.) of the trachytic regions in the Italian islands, agree with my observations at Ascension. Many passages might have been transferred without alteration from the works of the above authors, and would have been applicable to this island. They all agree in the laminated and stratified character of the whole series; and Humboldt speaks of some of the beds of obsidian being ribboned like jasper. (In Mr. Stokes' fine collection of obsidians from Mexico, I observe that the sphaerulites are generally much larger than those of Ascension; they are generally white, opaque, and are united into distinct layers: there are many singular varieties, different from any at Ascension. The obsidians are finely zoned, in quite straight or curved lines, with exceedingly slight differences of tint, of cellularity, and of more or less perfect degrees of glassiness. Tracing some of the less perfectly glassy zones, they are seen to become studded with minute white sphaerulites, which become more and more numerous, until at last they unite and form a distinct layer: on the other hand, at Ascension, only the brown sphaerulites unite and form layers; the white ones always being irregularly disseminated. Some specimens at the Geological Society, said to belong to an obsidian formation from Mexico, have an earthy fracture, and are divided in the finest parallel laminae, by specks of a black mineral, like the augitic or hornblendic specks in the rocks at Ascension.) They all agree in the nodular or concretionary character of the obsidian, and of the passage of these nodules into layers. They all refer to the repeated alterations, often in undulatory planes, of glassy, pearly, stony, and crystalline layers: the crystalline layers, however, seem to be much more perfectly developed at Ascension, than in the above-named countries. Humboldt compares some of the stony beds, when viewed from a distance, to strata of a schistose sandstone. Sphaerulites are described as occurring abundantly in all cases; and they everywhere seem to mark the passage, from the perfectly glassy to the stony and crystalline beds. Beudant's account (Beudant "Voyage" tome 3 page 373.) of his "perlite lithoide globulaire" in every, even the most trifling particular, might have been written for the little brown sphaerulitic globules of the rocks of Ascension.

From the close similarity in so many respects, between the obsidian formations of Hungary, Mexico, Peru, and of some of the Italian islands, with that of Ascension, I can hardly doubt that in all these cases, the obsidian and the sphaerulites owe their origin to a concretionary aggregation of the silica, and of some of the other constituent elements, taking place whilst the liquified mass cooled at a certain required rate. It is, however, well-known, that in several places, obsidian has flowed in streams like lava; for instance, at Teneriffe, at the Lipari Islands, and at Iceland. (For Teneriffe see von Buch "Descript. des Isles Canaries" pages 184 and 190; for the Lipari Islands see Dolomieu "Voyage" page 34; for Iceland see Mackenzie "Travels" page 369.) In these cases, the superficial parts are the most perfectly glassy, the obsidian passing at the depth of a few feet into an opaque stone. In an analysis by Vauquelin of a specimen of obsidian from Hecla, which probably flowed as lava, the proportion of silica is nearly the same as in the nodular or concretionary obsidian from Mexico. It would be interesting to ascertain, whether the opaque interior portions and the superficial glassy coating contained the same proportional constituent parts: we know from M. Dufrenoy ("Memoires pour servir a une Descript. Geolog. de la France" tome 4 page 371.) that the exterior and interior parts of the same stream of lava sometimes differ considerably in their composition. Even should the whole body of the stream of obsidian turn out to be similarly composed with nodular obsidian, it would only be necessary, in accordance with the foregoing facts, to suppose that lava in these instances had been erupted with its ingredients mixed in the same proportion, as in the concretionary obsidian.

LAMINATION OF VOLCANIC ROCKS OF THE TRACHYTIC SERIES.

We have seen that, in several and widely distant countries, the strata alternating with beds of obsidian, are highly laminated. The nodules, also, both large and small, of the obsidian, are zoned with different shades of colour; and I have seen a specimen from Mexico in Mr. Stokes' collection, with its external surface weathered (MacCulloch states "Classification of Rocks" page 531 that the exposed surfaces of the pitchstone dikes in Arran are furrowed "with undulating lines, resembling certain varieties of marbled paper, and which evidently result from some corresponding difference of laminar structure.") into ridges and furrows, corresponding with the zones of different degrees of glassiness: Humboldt ("Personal Narrative" volume 1 page 222.), moreover, found on the Peak of Teneriffe, a stream of obsidian divided by very thin, alternating, layers of pumice. Many other lavas of the feldspathic series are laminated; thus, masses of common trachyte at Ascension are divided by fine earthy lines, along which the rock splits, separating thin layers of slightly different shades of colour; the greater number, also, of the embedded crystals of glassy feldspar are placed lengthways in the same direction. Mr. P. Scrope ("Geological Transactions" volume 2 second series page 195.) has described a remarkable columnar trachyte in the Panza Islands, which seems to have been injected into an overlying mass of trachytic conglomerate: it is striped with zones, often of extreme tenuity, of different textures and colours; the harder and darker zones appearing to contain a larger proportion of silica. In another part of the island, there are layers of pearlstone and pitchstone, which in many respects resemble those of Ascension. The zones in the columnar trachyte are generally contorted; they extend uninterruptedly for a great length in a vertical direction, and apparently parallel to the walls of the dike-like mass. Von Buch ("Description des Iles Canaries" page 184.) has described at Teneriffe, a stream of lava containing innumerable thin, plate-like crystals of feldspar, which are arranged like white threads, one behind the other, and which mostly follow the same direction. Dolomieu ("Voyage aux Isles de Lipari" pages 35 and 85.) also states, that the grey lavas of the modern cone of Vulcano, which have a vitreous texture, are streaked with parallel white lines: he further describes a solid pumice-stone which possesses a fissile structure, like that of certain micaceous schists. Phonolite, which I may observe is often, if not always, an injected rock, also, often has a fissile structure; this is generally due to the parallel position of the embedded crystals of feldspar, but sometimes, as at Fernando Noronha, seems to be nearly independent of their presence. (In this case, and in that of the fissile pumice-stone, the structure is very different from that in the foregoing cases, where the laminae consist of alternate layers of different composition or texture. In some sedimentary formations, however, which apparently are homogeneous and fissile, as in glossy clay-slate, there is reason to believe, according to D'Aubuisson, that the laminae are really due to excessively thin, alternating, layers of mica.) From these facts we see, that various rocks of the feldspathic series have either a laminated or fissile structure, and that it occurs both in masses which have injected into overlying strata, and in others which have flowed as streams of lava.

The laminae of the beds, alternating with the obsidian at Ascension, dip at a high angle under the mountain, at the base of which they are situated; and they do not appear as if they had been inclined by violence. A high inclination is common to these beds in Mexico, Peru, and in some of the Italian islands (See Phillips "Mineralogy" for the Italian Islands page 136. For Mexico and Peru see Humboldt "Essai Geognostique." Mr. Edwards also describes the high inclination of the obsidian rocks of the Cerro del Navaja in Mexico in the "Proc. of the Geolog. Soc." June 1838.): on the other hand, in Hungary, the layers are horizontal; the laminae, also, of some of the lava-streams above referred to, as far as I can understand the descriptions given of them, appear to be highly inclined or vertical. I doubt whether in any of these cases, the laminae have been tilted into their present position; and in some instances, as in that of the trachyte described by Mr. Scrope, it is almost certain that they have been originally formed with a high inclination. In many of these cases, there is evidence that the mass of liquified rock has moved in the direction of the laminae. At Ascension, many of the air-cells have a drawn out appearance, and are crossed by coarse semi-glassy fibres, in the direction of the laminae; and some of the layers, separating the sphaerulitic globules, have a scored appearance, as if produced by the grating of the globules. I have seen a specimen of zoned obsidian from Mexico, in Mr. Stokes' collection, with the surfaces of the best-defined layers streaked or furrowed with parallel lines; and these lines or streaks precisely resembled those, produced on the surface of a mass of artificial glass by its having been poured out of a vessel. Humboldt, also, has described little cavities, which he compares to the tails of comets, behind sphaerulites in laminated obsidian rocks from Mexico, and Mr. Scrope has described other cavities behind fragments embedded in his laminated trachyte, and which he supposes to have been produced during the movement of the mass. ("Geological Transactions" volume 2 second series page 200 etc. These embedded fragments, in some instances, consist of the laminated trachyte broken off and "enveloped in those parts, which still remained liquid." Beudant, also, frequently refers in his great work on "Hungary" tome 3 page 386, to trachytic rocks, irregularly spotted with fragments of the same varieties, which in other parts form the parallel ribbons. In these cases, we must suppose, that after part of the molten mass had assumed a laminated structure, a fresh irruption of lava broke up the mass, and involved fragments, and that subsequently the whole became relaminated.) From such facts, most authors have attributed the lamination of these volcanic rocks to their movement whilst liquified. Although it is easy to perceive, why each separate air-cell, or each fibre in pumice-stone (Dolomieu "Voyage" page 64.), should be drawn out in the direction of the moving mass; it is by no means at first obvious why such air-cells and fibres should be arranged by the movement, in the same planes, in laminae absolutely straight and parallel to each other, and often of extreme tenuity; and still less obvious is it, why such layers should come to be of slightly different composition and of different textures.

In endeavouring to make out the cause of the lamination of these igneous feldspathic rocks, let us return to the facts so minutely described at Ascension. We there see, that some of the thinnest layers are chiefly formed by numerous, exceedingly minute, though perfect, crystals of different minerals; that other layers are formed by the union of different kinds of concretionary globules, and that the layers thus formed, often cannot be distinguished from the ordinary feldspathic and pitchstone layers, composing a large portion of the entire mass. The fibrous radiating structure of the sphaerulites seems, judging from many analogous cases, to connect the concretionary and crystalline forces: the separate crystals, also, of feldspar all lie in the same parallel planes. (The formation, indeed, of a large crystal of any mineral in a rock of mixed composition implies an aggregation of the requisite atoms, allied to concretionary action. The cause of the crystals of feldspar in these rocks of Ascension, being all placed lengthways, is probably the same with that which elongates and flattens all the brown sphaerulitic globules (which behave like feldspar under the blowpipe) in this same direction.) These allied forces, therefore, have played an important part in the lamination of the mass, but they cannot be considered the primary force; for the several kinds of nodules, both the smallest and largest, are internally zoned with excessively fine shades of colour, parallel to the lamination of the whole; and many of them are, also, externally marked in the same direction with parallel ridges and furrows, which have not been produced by weathering.

Some of the finest streaks of colour in the stony layers, alternating with the obsidian, can be distinctly seen to be due to an incipient crystallisation of the constituent minerals. The extent to which the minerals have crystallised can, also, be distinctly seen to be connected with the greater or less size, and with the number, of the minute, flattened, crenulated air-cavities or fissures. Numerous facts, as in the case of geodes, and of cavities in silicified wood, in primary rocks, and in veins, show that crystallisation is much favoured by space. Hence, I conclude, that, if in a mass of cooling volcanic rock, any cause produced in parallel planes a number of minute fissures or zones of less tension (which from the pent-up vapours would often be expanded into crenulated air-cavities), the crystallisation of the constituent parts, and probably the formation of concretions, would be superinduced or much favoured in such planes; and thus, a laminated structure of the kind we are here considering would be generated.

That some cause does produce parallel zones of less tension in volcanic rocks, during their consolidation, we must admit in the case of the thin alternate layers of obsidian and pumice described by Humboldt, and of the small, flattened, crenulated air-cells in the laminated rocks of Ascension; for on no other principle can we conceive why the confined vapours should through their expansion form air-cells or fibres in separate, parallel planes, instead of irregularly throughout the mass. In Mr. Stokes' collection, I have seen a beautiful example of this structure, in a specimen of obsidian from Mexico, which is shaded and zoned, like the finest agate, with numerous, straight, parallel layers, more or less opaque and white, or almost perfectly glassy; the degree of opacity and glassiness depending on the number of microscopically minute, flattened air-cells; in this case, it is scarcely possible to doubt but that the mass, to which the fragment belonged, must have been subjected to some, probably prolonged, action, causing the tension slightly to vary in the successive planes.

Several causes appear capable of producing zones of different tension, in masses semi-liquified by heat. In a fragment of devitrified glass, I have observed layers of sphaerulites which appeared, from the manner in which they were abruptly bent, to have been produced by the simple contraction of the mass in the vessel, in which it cooled. In certain dikes on Mount Etna, described by M. Elie de Beaumont ("Mem. pour servir" etc. tome 4 page 131.), as bordered by alternating bands of scoriaceous and compact rock, one is led to suppose that the stretching movement of the surrounding strata, which originally produced the fissures, continued whilst the injected rock remained fluid. Guided, however, by Professor Forbes' ("Edinburgh New Phil. Journal" 1842 page 350.) clear description of the zoned structure of glacier-ice, far the most probable explanation of the laminated structure of these feldspathic rocks appears to be, that they have been stretched whilst slowly flowing onwards in a pasty condition (I presume that this is nearly the same explanation which Mr. Scrope had in his mind, when he speaks ("Geolog. Transact." volume 2 second series page 228) of the ribboned structure of his trachytic rocks, having arisen, from "a linear extension of the mass, while in a state of imperfect liquidity, coupled with a concretionary process."), in precisely the same manner as Professor Forbes believes, that the ice of moving glaciers is stretched and fissured. In both cases, the zones may be compared to those in the finest agates; in both, they extend in the direction in which the mass has flowed, and those exposed on the surface are generally vertical: in the ice, the porous laminae are rendered distinct by the subsequent congelation of infiltrated water, in the stony feldspathic lavas, by subsequent crystalline and concretionary action. The fragment of glassy obsidian in Mr. Stokes' collection, which is zoned with minute air-cells must strikingly resemble, judging from Professor Forbes' descriptions, a fragment of the zoned ice; and if the rate of cooling and nature of the mass had been favourable to its crystallisation or to concretionary action, we should here have had the finest parallel zones of different composition and texture. In glaciers, the lines of porous ice and of minute crevices seem to be due to an incipient stretching, caused by the central parts of the frozen stream moving faster than the sides and bottom, which are retarded by friction: hence in glaciers of certain forms and towards the lower end of most glaciers, the zones become horizontal. May we venture to suppose that in the feldspathic lavas with horizontal laminae, we see an analogous case? All geologists, who have examined trachytic regions, have come to the conclusion, that the lavas of this series have possessed an exceedingly imperfect fluidity; and as it is evident that only matter thus characterised would be subject to become fissured and to be formed into zones of different tensions, in the manner here supposed, we probably see the reason why augitic lavas, which appear generally to have possessed a high degree of fluidity, are not, like the feldspathic lavas, divided into laminae of different composition and texture. (Basaltic lavas, and many other rocks, are not unfrequently divided into thick laminae or plates, of the same composition, which are either straight or curved; these being crossed by vertical lines of fissure, sometimes become united into columns. This structure seems related, in its origin, to that by which many rocks, both igneous and sedimentary, become traversed by parallel systems of fissures.) Moreover, in the augitic series, there never appears to be any tendency to concretionary action, which we have seen plays an important part in the lamination of rocks, of the trachytic series, or at least in rendering that structure apparent.

Whatever may be thought of the explanation here advanced of the laminated structure of the rocks of the trachytic series, I venture to call the attention of geologists to the simple fact, that in a body of rock at Ascension, undoubtedly of volcanic origin, layers often of extreme tenuity, quite straight, and parallel to each other, have been produced;-some composed of distinct crystals of quartz and diopside, mingled with amorphous augitic specks and granular feldspar,-others entirely composed of these black augitic specks, with granules of oxide of iron,-and lastly, others formed of crystalline feldspar, in a more or less perfect state of purity, together with numerous crystals of feldspar, placed lengthways. At this island, there is reason to believe, and in some analogous cases, it is certainly known, that the laminae have originally been formed with their present high inclination. Facts of this nature are manifestly of importance, with relation to the structural origin of that grand series of plutonic rocks, which like the volcanic have undergone the action of heat, and which consist of alternate layers of quartz, feldspar, mica and other minerals.